Brønsted-Lowry Acids & Bases (College Board AP Chemistry)

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Brønsted-Lowry Acids & Bases

  • The Brønsted-Lowry theory defines acids and bases in terms of proton transfer
    • A Brønsted-Lowry acid donates a proton (H+)
    • A Brønsted-Lowry base receive a proton (H+)
  • The Brønsted-Lowry theory is not limited to the aqueous state, therefore, the principle can be applied to reactions in the gas phase

Brønsted-Lowry acid reacting with a Brønsted-Lowry base

Equilibrium of a Brønsted-Lowry acid and base

The Brønsted-Lowry acid donates a proton to the Brønsted-Lowry base that accepts a proton

Worked example

Identify the Brønsted-Lowry acid and the Brønsted-Lowry base in the following chemical reaction

H2SO4(aq) + H2O(l) → HSO4(aq) + H3O+(aq)

 

Brønsted-Lowry acid

Brønsted-Lowry base

(A)

H2SO4

 H3O+

(B)

H2SO4

H2O

(C)

H2O

H3O+

(D)

H2O

H2SO4

 

Answer:

  • The correct option is B
    • H2SO4 donate a proton to H2O
    • So, H2SO4 must be the Brønsted-Lowry acid and H2O the Brønsted-Lowry base

Water as a Brønsted-Lowry Acid & Base

  • A lot of acid-base reactions occur in aqueous state
  • Water can act both as a Brønsted-Lowry acid and Brønsted-Lowry base
    • Species that can donate or receive protons are called amphiprotic

Water as a Brønsted-Lowry acid

Diagram showing how water acts as Brønsted-Lowry acid

Diagram to show how water is amphoteric

Water as a Brønsted-Lowry acid donates one proton to ammonia

Lewis structure for the reaction between water and ammonia

The Lewis diagram for the reaction of water with ammonia

Lewis structures that show the reaction between water and ammonia, and the charges they acquire when they become ions

Water as a Brønsted-Lowry base

Diagram showing how water acts as Brønsted-Lowry base

water-reacting-with-hcl

Water as a Brønsted-Lowry base receives a proton from the hydrochloric acid

Lewis structure for the reaction between water and hydrochloric acid

The Lewis diagram for the reaction of water and HCl

Lewis structures that show the reaction between water and hydrochloric acid, and the charges they acquire when they become ions

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Martín

Author: Martín

Martín, a dedicated chemistry teacher and tutor, excels in guiding students through IB, AP, and IGCSE Chemistry. As an IB Chemistry student, he came from hands-on preparation, focusing on practical exam techniques and rigorous practice. While at Universidad San Francisco de Quito, his academic journey sparked a passion for computational and physical chemistry. Martín specializes in chemistry, and he knows that SaveMyExams is the right place if he wants to have a positive impact all around the world.