Atomic Structure (Oxford AQA IGCSE Physics)

Revision Note

Caroline Carroll

Expertise

Physics Subject Lead

Atomic Structure

  • Atoms are the building blocks of all matter

  • They are incredibly small, with a radius of only 1 × 10-10 m

    • This means that about one hundred million atoms could fit side by side across your thumbnail

  • Atoms have a tiny, dense nucleus at their centre, with electrons orbiting around the nucleus

  • The radius of the nucleus is much smaller (over 10,000 times smaller) than the whole atom, but it contains almost all of the mass of the atom

Parts of the atom

  • The nucleus contains:

    • Protons - positively charged particles with a relative atomic mass of one unit

    • Neutrons – no charge, and also with a relative atomic mass of one unit

  • Almost all of the atom is empty space, but moving around the nucleus there are:

    • Electrons – negative charge with almost no mass (1/2000 the mass of a proton or neutron)

The structure of an atom

Atomic structure showing a central nucleus with orbiting electrons, for GCSE Physics revision notes
Diagram showing the structure of a lithium atom. If drawn to scale, the electrons would be around 100 metres away from the nucleus!
  • The properties of each of the particles are shown in the table below:

Table of the Relative Masses and Charges

Particle

Location

Relative Charge

Relative Mass

Proton

In the nucleus

+1

1

Neutron

In the nucleus

0

1

Electron

Orbiting the nucleus

-1

1/2000 (Negligible)

Exam Tip

There are many different models of the atom. As you progress through the topic, you will discover that the atom can also be described using the 'plum pudding' model, but for your exam, only use the model and descriptions described here!

Be careful with your terminology:

  • Atom = nucleus (proton and neutron) and electrons

  • Nucleus = protons and neutrons at the centre of the atom

Atomic & Mass Number

Atomic number

  • The number of protons in an atom is called its atomic number (it can also be called the proton number)

    • Elements in the periodic table are ordered by their atomic number

    • Therefore, the number of protons determines which element an atom is

  • The atomic number of a particular element is always the same

  • For example:

    • Hydrogen has an atomic number of 1. It always has just one proton

    • Sodium has an atomic number of 11. It has 11 protons

    • Uranium has an atomic number of 92. It has 92 protons

  • The atomic number is also equal to the number of electrons in an atom

    • This is because atoms have the same number of electrons and protons to have no overall charge

    • For more information, see the revision note on Atoms & Ions

Mass number

  • The total number of particles in the nucleus of an atom is called its mass number

  • The mass number is the number of protons and neutrons in the atom

  • The number of neutrons can be found by subtracting the atomic number from the mass number

Number of Neutrons = Mass Number - Atomic Number

  • For example, if a sodium atom has a mass number of 23 and an atomic number of 11:

    • It has 23 particles in its nucleus

    • 11 of them are protons

    • So the number of neutrons would be 23 – 11 = 12

Nuclear notation

  • The mass number and atomic number of an atom are shown by writing them with the atomic symbol

    • This is called nuclear notation

Examples of nuclear notation

Nuclear Notation of different elements, IGCSE & GCSE Physics revision notes
Examples of nuclear notation for atoms of hydrogen, sodium and uranium
  • The top number is the mass number

    • This is equal to the total number of particles (protons and neutrons) in the nucleus

  • The lower number is the atomic number

    • This is equal to the total number of protons in the nucleus

  • The atomic and mass numbers of each type of atom in the examples above are shown in this table:

Calculating the Number of Protons, Neutrons and Electrons

Atom

Number of Protons (Atomic Number)

Number of Neutrons (Mass Number - Atomic Number)

Number of Electrons (Same as the Number of Protons)

Hydrogen

1

1

1

Sodium

11

12

11

Uranium

92

143

92

Worked Example

The element symbol for gold is Au. How many protons, neutrons and electrons are in the gold atom?

Au presubscript 79 presuperscript 197

Protons

Neutrons

Electrons

A

79

79

79

B

197

79

118

C

118

118

79

D

79

118

79

Answer:  D

Step 1: Determine the atomic and mass number

  • The gold atom has an atomic number of 79 (smaller number) and a mass number of 197 (larger number)

Step 2: Determine the number of protons

  • The atomic number is equal to the number of protons

  • The atom has 79 protons

Step 3: Calculate the number of neutrons

  • The mass number is equal to the number of protons and neutrons

  • The number of neutrons is equal to the mass number minus the atomic number

    • If there are 197 particles in the nucleus and 79 of them are protons

    • Then the number of neutrons is

197 - 79 = 118

  • The atom has 118 neutrons

Step 4: Determine the number of electrons

  • An atom has the same number of protons and electrons

  • The atom has 79 electrons

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Caroline Carroll

Author: Caroline Carroll

Caroline graduated from the University of Nottingham with a degree in Chemistry and Molecular Physics. She spent several years working as an Industrial Chemist in the automotive industry before retraining to teach. Caroline has over 12 years of experience teaching GCSE and A-level chemistry and physics. She is passionate about creating high-quality resources to help students achieve their full potential.