Properties of Giant Covalent Structures (Oxford AQA IGCSE Chemistry)

Revision Note

Alexandra Brennan

Expertise

Chemistry

Melting & Boiling Points of Giant Covalent Structures

  • Covalent bonding can be responsible for substances that have many different structures and therefore different physical properties

  • We have already seen how simple molecules such as H2O and N2 form covalently bonded molecules with a fixed number of atoms

  • Some covalent structures have a huge number of non-metal atoms bonded to other non-metal atoms via strong covalent bonds

    • They are called giant structures or macromolecules

  • Examples include diamond, graphite and silicon dioxide

    • Diamond and graphite are made from carbon atoms 

    • Silicon dioxide (silica) is made from silicon and oxygen atoms

  • All giant covalent structures have high melting points because:

    • There are strong covalent bonds between atoms

    • These require lots of energy to overcome 

Giant covalent structures

Diagram showing three giant covalent structures; diamond, graphite and silicon dioxide
Diamond and graphite are made from carbon atoms, silicon dioxide from silicon and oxygen

Exam Tip

Make sure you can recognise diamond, graphite and silicon dioxide from diagrams!

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Alexandra Brennan

Author: Alexandra Brennan

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.