Syllabus Edition

First teaching 2023

First exams 2025

|

Intermolecular Forces, Electronegativity & Bond Properties (CIE A Level Chemistry)

Topic Questions

11 mark

Silver and iodine are both shiny crystalline solids. 

Which forces exist between neighboring iodine molecules in solid iodine and particles in solid silver?

 

Iodine

Silver

A

Metallic bonds

Covalent bonds

B

Ionic bonds

Metallic

C

Covalent bonds

Covalent bonds

D

Van der Waals’ forces

Metallic

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21 mark

Below are four solids. Which of these contains more than one kind of bonding?

  • Diamond

  • Sodium chloride

  • Iron

  • Ice

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31 mark

Which quantity gives the best indication of the relative strengths of the hydrogen bonds between water molecules in the liquid state?

  • Enthalpy changes of vaporisation

  • Bond dissociation energies

  • Enthalpy of formation

  • Activation energy

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11 mark

1.00g of propanone is reacted with 5.00g of ethane-1,2-diol and the strong acid benzene sulphonic acid, C6H5SO3H. The mixture is heated under reflux in an inert solvent.

1-3-h-1

Which of the following statements is not correct?

  • Propanone has a higher melting point than ethane-1,2-diol

  • Both products are polar molecules

  • Ethane-1,2-diol is soluble in water

  • Water has a higher melting point than liquid Y

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21 mark

Hydrogen bonding occurs between molecules of liquid methanal, HCHO, and molecules of liquid Y. Which of the following is most likely to be liquid Y?

  • CH3CO2CH3

  • CH3OH

  • CH3COCH3

  • CH3CHO

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31 mark

CHCl3 and Br2 are both liquids at room temperature due to the existence of dipoles.

What dipoles are involved within CHCl3 and Br2

 

CHCl3

Br2

A

Induced dipoles only

Induced dipoles only

B

Induced dipoles only

Induced dipoles and permanent dipoles

C

Induced dipoles and permanent dipoles

Induced dipoles and permanent dipoles

D

Induced dipoles and permanent dipoles

Induced dipoles only

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11 mark

Which of the following changes of state shows only dispersion van der Waals’ forces being overcome?

  • C3H6 (l) rightwards arrow C3H6 (s)

  • CO2 (l) rightwards arrow CO2 (g)

  • H2O (s) rightwards arrow H2O (l)

  • C2H5OH (l) rightwards arrow C2H5OH (g)

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21 mark

Which of the following molecules has the biggest overall dipole?

  • 1-3-m-9a

  • 1-3-m-9b

  • 1-3-m-9c

  • 1-3-m-9d

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31 mark

What is the strongest type of intermolecular force exhibited in the amino acid molecule serine?

Serine

Serine

  • London dispersion forces 

  • Permanent dipole-dipole forces

  • Hydrogen bonding

  • Covalent bonding

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