This question is about organic compounds found in living organisms.
Terpenes are a class of organic compounds widely used as fragrances in products such as perfumes. For example, one of the simpler terpenes, nerol is found in many essential oils such as lemongrass and hops. The structure of nerol is shown in Fig 1.1.
Explain whether nerol shows geometrical (cis-trans) and optical isomerism. In your answer, identify any relevant points in the structure of nerol.
Two structural isomers of nerol are linalool and geraniol. They are unsaturated alcohols with similar chemical properties that are both used in perfumes.
The IUPAC names for both linalool and geraniol are shown in Table 1.1.
Isomer |
IUPAC name |
Linalool |
3,7-dimethylocta-1,6-dien-3-ol |
Geraniol |
3,7-dimethylocta-2,6-dien-1-ol |
Draw the skeletal formulae for these two isomeric alcohols.
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