Syllabus Edition

First teaching 2023

First exams 2025

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The Reactions of Chlorine (CIE A Level Chemistry)

Topic Questions

11 mark

Chlorine is widely used in water treatment plants. Chlorine is reacted with water to produce hydrochloric acid and another chlorine-containing acid.

Which row correctly describes the properties of the reaction? 

 

Moles Cl2 used

Moles HCl produced

Other product formed

A

B

C

D

1

2

3

4

1

3

5

7

HClO

HClO2

HClO3

HClO4

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21 mark

When chlorine reacts with cold sodium hydroxide the following reaction occurs

Cl2 (aq) + 2NaOH (aq) → NaCl (aq) + NaClO (aq) + H2O (l)

Which of the following statements is correct?

  • The chlorine has only been oxidised 

  • The oxidation number of Cl in NaClO is 0

  • The chlorine is simultaneously oxidised and reduced 

  • The oxidation number of Cl in Cl2 is -1 

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31 mark

When chlorine reacts with hot sodium hydroxide the following reaction occurs.

3Cl2 (g) + 6NaOH (aq) → 5NaCl (aq) + NaClO3 (aq) + 3H2O (l)

Which row shows the correct oxidation state of chlorine in each ion?

 

Cl2

NaCl

NaClO3

A

B

C

D

0

0

0

0

-1

+1

+1

-1

+5

-5

-3

+3

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41 mark

Chlorine is used to treat drinking water. 

Which statement is correct?

  • Water reacts with chlorine to form hydrochloric acid and chloric(I) acid, HClO

  • When universal indicator is added to chloric(I) acid, HClO it turns blue then white

  • Chloric acid does not dissociate further when added to water

  • Chlorine reacts with cold sodium hydroxide to form sodium chloride and water only

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11 mark

When chlorine is bubbled through aqueous sodium hydroxide solution different substances are formed depending on the conditions. Which statement is incorrect? 

  • In hot NaOH (aq), ClO3 (aq) ions are formed.

  • In cold NaOH (aq), ClO (aq) ions are formed.

  • The oxidation state of chlorine changes from 0 to +3

  • Disproportionation of chlorine occurs in both cold and hot aqueous solutions.

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21 mark

Which statement accurately describes the role of chlorine in the reaction with water?

  • Chlorine undergoes only oxidation in the reaction, resulting in the formation of ClO(aq)

  • Chlorine undergoes only reduction in the reaction, resulting in the formation of Cl (aq)

  • Chlorine undergoes both oxidation and reduction in the reaction, forming ClO (aq) and Cl (aq)

  • The oxidation state of chlorine changes from 0 to +5

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31 mark

A few drops of sodium chlorate (I) solution is added to potassium bromide solution. A red-brown gas is produced along with sodium chloride solution.

Which of the following statements is correct?

  • The oxidation state of chlorine in NaClO is +5

  • Chlorine gas is produced

  • Bromide ions are oxidised in this reaction  

  • NaClO is the reducing agent 

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11 mark

When the yellow liquid NCl3 is stirred into aqueous sodium hydroxide, the reaction that occurs can be represented by the following equation.

2NCl3 (l) + 6NaOH (aq) rightwards arrow N2 (g) + 3NaCl (aq) + 3NaClO (aq) + 3H2O (l)

Which of the following is not correct for this reaction?

  • A bleaching solution remains after the reaction.

  • Effervescence will be observed.

  • The nitrogen is oxidised.

  • The final solution gives a precipitate with acidified silver nitrate.

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21 mark

Which is the correct equation for the reaction of hot, dilute aqueous sodium hydroxide, NaOH, and chlorine, Cl2?

  • Cl2 + 2NaOH → NaCl + NaClO + H2O

  • 1 halfCl2 + 2OH- → ClO- + H2O + e-

  • begin mathsize 16px style 1 half end styleCl2 + 6OH- → ClO3- + 3H2O + e-

  • 3Cl2 + 6NaOH → 3NaCl + 3NaClO3 + H2O

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31 mark

What is the main disinfectant formed when chlorine gas is added to water during purification?

  • HClO

  • HCl

  • ClO2 

  • CHCl3 

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