4.2 Crude Oil (Edexcel IGCSE Chemistry)

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  • What is crude oil?

    Crude oil is a mixture of different hydrocarbons.

  • True or False?

    Each fraction in crude oil consists of groups of hydrocarbons with similar chain lengths.

    True.

    Each fraction in crude oil consists of groups of hydrocarbons with similar chain lengths.

  • Define fractional distillation.

    Fractional distillation is the process of separating the different fractions of crude oil based on their boiling points.

  • True or False?

    The size and length of each hydrocarbon molecule determines which fraction it will be separated into.

    True.

    The size and length of each hydrocarbon molecule determines which fraction it will be separated into.

  • True or False?

    As you move up a fractionating column, the temperature increases.

    False.

    As you move up a fractionating column, the temperature decreases.

  • What happens to the viscosity of a liquid as the number of carbon atoms increases?

    As the number of carbon atoms increases, the viscosity of the liquid increases.

  • What happens to the volatility of a hydrocarbon liquid as the molecular size increases?

    As the molecular size increases, the volatility of a hydrocarbon liquid decreases.

  • Define the term viscosity.

    Viscosity is the ease of flow of a liquid.

  • What is the use of liquefied petroleum gas?

    Liquefied petroleum gas is used for domestic heating & cooking.

  • True or False?

    Kerosene is used as jet fuel.

    True.

    Kerosene is used as jet fuel (paraffin).

  • What is diesel used for?

    Diesel is used in diesel engines (gas oil).

  • Give a use of heavy fuel oil.

    Heavy fuel oil is used for ships & power stations.

  • Which fraction is used to surface roads?

    The fraction used for surfacing roads is bitumen.

  • What are the products of complete combustion of hydrocarbons?

    The products of complete combustion of hydrocarbons are carbon dioxide and water.

  • Define incomplete combustion.

    Incomplete combustion occurs when there is insufficient oxygen to burn the fuel completely.

  • What are the products of incomplete combustion?

    The products of incomplete combustion are carbon monoxide, carbon (soot) and water.

  • How does carbon monoxide cause harm?

    Carbon monoxide binds well to haemoglobin, preventing it from binding to oxygen and transporting oxygen to organs.

  • True or False?

    Carbon dioxide is not a pollutant causing global warming and climate change.

    False.

    Carbon dioxide is a pollutant causing global warming and climate change.

  • Name one place that incomplete combustion can occur.

    Incomplete combustion occurs in some appliances such as:

    • Boilers

    • Stoves 

    • Internal combustion engines

  • What is the symbol equation for the complete combustion of propane?

    The symbol equation for the complete combustion of propane is:

    C3H+ 5O2 → 3CO2 + 4H2O

  • Balance the following symbol equation for the incomplete combustion of ethane.

    C2H6 + O2 → CO + H2O

    The balanced symbol equation for the incomplete combustion of ethane is:

    C2H6 + 2.5O2 → 2CO + 3H2O

  • Name three gases that the burning of fossil fuels releases.

    Three gases that the burning of fossil fuels releases:

    • Carbon dioxide

    • Carbon monoxide

    • Oxides of nitrogen

    • Oxides of sulfur

  • Where are nitrogen oxides formed?

    Nitrogen oxides are formed in the high pressure and temperature conditions of internal combustion engines and blast furnaces.

  • State the equation for sulfur being oxidised to sulfur dioxide.

    The equation for the oxidation of sulfur is:

    S (s) + O2 (g) → SO2 (g)

  • How is acid rain formed from nitrogen and sulfur oxides?

    Acid rain is formed by nitrogen and sulfur oxides dissolve in rainwater to form nitric acid and sulfuric acid, respectively.

  • What are two harmful effects of sulfur dioxide?

    Harmful effects of sulfur dioxide include:

    • Acid rain

    • Corrosion of buildings and structures

    • Damage to aquatic organisms

    • Damage to plant life

    • Respiratory problems

  • How do catalytic converters work?

    Catalytic converters contain transition metal catalysts that convert pollutant gases to less harmful substances through redox reactions.

  • State the equation for nitrogen oxides (NO and NO2) being reduced to nitrogen and oxygen.

    The equations for the reduction of nitrogen oxides are:

    2NO → N2 + O2

    2NO2 → N2 + 2O2

  • Name the two gases that contribute to acid rain.

    Two gases that contribute to acid rain are nitrogen dioxide and sulfur dioxide.

  • How is sulfur dioxide produced from the burning of fossil fuels?

    During combustion, the sulfur impurities in the fossil fuels get oxidised / react with oxygen to form sulfur dioxide.

  • Write an equation to show the formation of acid rain, H2SO4 (aq), from sulfur dioxide, water and oxygen.

    The equation to show the formation of acid rain, H2SO4 (aq), from sulfur dioxide, water and oxygen is:

    2SO2 (g) + O2 (g) + 2H2O (l) → 2H2SO(aq)

  • What is the purpose of cracking?

    The purpose of cracking is to convert surplus unwanted fractions of crude oil, such as kerosene and diesel oil, into more useful fractions like petrol (gasoline), alkenes, and hydrogen.

  • True or False?

    The demand for certain fractions outstrips the supply, which is why cracking is necessary.

    True.

    The demand for certain fractions outstrips the supply, which is why cracking is necessary to convert surplus unwanted fractions into more useful ones.

  • What are the two methods used for cracking alkanes?

    The two methods used for cracking alkanes are:

    • Catalytic cracking

    • Steam cracking

  • True or False?

    Cracking is an exothermic reaction.

    False.

    Cracking is an endothermic reaction.

  • What is the equation for the cracking of decane to produce octane and ethene?

    The equation for the cracking of decane to produce octane and ethene is:

    C10H22 → C8H18 + C2H4

  • True or False?

    Alkanes are saturated compounds, and alkenes are unsaturated compounds.

    True.

    Alkanes are saturated compounds, and alkenes are unsaturated compounds.

  • Name the catalyst used in catalytic cracking.

    The catalyst used in catalytic cracking is:

    • Alumina / aluminium oxide / Al2O3
      OR

    • Silica / silicon dioxide / SiO2

  • True or False?

    Cracking is a type of substitution reaction.

    False:

    Cracking is a type of thermal decomposition reaction.

  • True or False?

    Long chain fractions are in high supply but in low demand.

    True.

    Long chain fractions are in high supply but in low demand.

    This explains why they are cracked into more useful, shorter chain alkanes and alkenes.

  • Name a longer chain fraction of crude oil.

    Examples of longer chain fractions of crude oil are:

    • Fuel oil

    • Bitumen