The photograph shows a vase made of uranium glass. Uranium glass is radioactive.
Uranium glass usually contains a maximum of 2% uranium. Uranium glass made in the early part of the 20th century can contain up to 25% uranium.
A student carried out an investigation to determine the percentage of uranium in the glass.
The student measured the count rate by placing a Geiger Muller (GM) tube against the vase at a single position. This value was used to calculate the decay rate for the whole vase.
i)
Show that the decay constant for uranium is about 5 × 10−18 s−1
half-life of uranium = 1.41 × 1017 s
(2)
ii)
Calculate the percentage of uranium, by mass, in the glass.
area of GM tube window = 6.36 × 10−5 m2
surface area of vase = 0.0177 m2
background count rate = 525 counts in 10 minutes
count rate when GM tube next to vase = 3623 counts in 5 minutes
mass of vase = 149 g
mass of uranium atom = 238 u
(6)
Percentage of uranium = ....................................................................
iii)
The uranium decays by emitting alpha particles.
Criticise the method used to determine the percentage of uranium in the vase.
(2)