7.1 Equilibrium

A 0.680 mol sample of SO₃ is introduced into a reaction container and allowed to reach equilibrium at temperature T. 

2SO₃ (g) ⇌ 2SO₂ (g) + O₂ (g)                ΔH = +196 kJ mol^-1

The value of K_c for the reaction was 7.9 x 10^-3 mol dm^-3.

The size of the container for the reaction is increased. State the effect if any on the equilibrium constant, K_c, and the position of equilibrium. Justify your answer.

The temperature of the reaction in part (a) is increased. State the effect, if any, on the equilibrium constant, K_c, and the position of equilibrium. Justify your answer.

If the value of the equilibrium constant, K_c, is 2.7 x 10^-2 at temperature T1 for the reaction:

2SO₃ (g) ⇌ 2SO₂ (g) + O₂ (g)

 Calculate the equilibrium constant, K_c, for the reaction:

4SO₂ (g) + 2O₂ (g) ⇌ 4SO₃ (g)

Give your answer to 2 decimal places.

A mixture in a container at temperature, T, is allowed to reach equilibrium.

2E (g) ⇌ 2F (g) + G (g)     ΔH = -143 kJ mol^-1

The value of K_c for the reaction at T is 2.98 mol dm^-3. Comment on the relationship between the concentration of the reactant E and products F and G with regards to K_c.

Reactants G and H react together to form products J and K according to the equation

3G + H ⇌ 4J + K

Write the expression for the equilibrium constant, K_c.

Diesters are compounds often used as synthetic lubricants for machinery such as compressors. The reaction below shows the formation of a diester from propanoic acid and propane-1,3-diol. 

2CH₃CH₂COOH + HOCH₂CH₂CH₂OH ⇌ C₉H₁₆O₄ + 2H₂O

The value for K_c at temperature, T, is 1.29.

The forward reaction is slightly exothermic. At a different temperature, T1, the value for K_c increases to 22.78. 

State whether the new temperature, T1, is higher or lower than the original temperature. Justify your answer.

The graph below shows the effect of pressure and temperature on the equilibrium yield of gaseous molecules.

Using the graph, explain whether the forward reaction is exothermic or endothermic.

Use the graph to explain whether the forward reaction will involve either an increase or decrease in the number of moles of a gas.

The graph to show the relationship between temperature and K_c for a different dynamic equilibrium to produce a gaseous product is shown below.

Use the information shown in the graph to establish whether the forward reaction is exothermic or endothermic. Justify your answer.

Sulfuric acid is produced on an industrial scale in the Contact Process. The middle step of the process involves the following equilibrium reaction:               

2SO₂ (g) + O₂ (g) ⇌ 2SO₃ (g)               ∆H = -198 kJ 

K_c >> 1 at 200 C and 100 kPa

Outline what the information given about K_c tells you about the extent of the reaction at the conditions specified.

The actual operating conditions of the Contact Process are 450 C and 200 kPa. Explain the choice of using these operating conditions in terms of temperature and pressure.

Suggest, with a reason, whether using pure oxygen instead of air would be an improvement to the Contact Process.

Write the equilibrium constant expression for the reverse reaction of the Contact Process.

A sample of chlorine gas is reacted with sulfur dioxide at 375 ^oC in a 1dm³ container. The equilibrium reaction produces colourless sulfuryl chloride, SO₂Cl₂, and the enthalpy change for the reaction is -84 kJ mol^-1.

Write the equation for the reaction and deduce the equilibrium constant expression.

If the reaction in part (a) is carried out at 300 ^oC, predict what will happen to the equilibrium concentration of SO₂Cl₂ and the value of K_c. Explain your answer. 

If the reaction in (a) is now carried out in a 2.00 dm³ container, predict, with a reason what will happen to the equilibrium concentration of SO₂Cl₂ and the value of K_c.

If the same reaction is carried out in part (a) with a catalyst, explain how this will affect the equilibrium concentration of SO₂Cl₂.

A reaction mixture was set up in a syringe containing dinitrogen tetraoxide gas and nitrogen dioxide gas as shown in the equation below:

N₂O₄ (g) ⇋ 2NO₂ (g)                ?H = +58 kJ mol^-1

The appearance of the gases is quite different; dinitrogen tetraoxide is a pale-yellow gas, whereas nitrogen dioxide is dark brown in colour.

State why this equilibrium reaction is considered homogeneous and deduce the equilibrium constant expression for the reaction.

Explain why the reaction mixture turns darker in colour when it is heated. 

The reaction which takes place in part (a) has a K_c value of 3.21. A student claims that increasing the temperature of this reaction will increase the value of K_c.

Is the student correct? Justify your answer.

Using Le Chatelier’s principle, explain what would be seen if the plunger of the syringe was pressed and the gases within the syringe were compressed.

During an esterification reaction, methanol and ethanoic acid react together to form the ester, methyl ethanoate, and water as shown below:

CH₃OH (l)  +  CH₃COOH (l)  ⇋  CH₃COOCH₃ (l)  +  H₂O (l)    K_c = 7.21 at 298K

A chemist sets up the reaction and allows it to reach dynamic equilibrium at a constant temperature.

Once the reaction in part (a) is set up, the chemist leaves it for 24 hours to make sure that it has reached equilibrium.

State how the chemist could check to make sure that the reaction mixture had reached equilibrium.

When the chemist sampled the concentrations of the substances in the reaction mixture and calculated a value for the reaction quotient, she determined the value of Q to be 5.34. 

Adding more ethanoic acid to the reaction mixture will increase the yield of the ester produced.

Use Le Chatelier’s principle to explain the above statement.