5.3 Acids, Bases & Buffers

This question is about acid-base reactions.

Calculate the volume of water in cm³ required to raise the pH of 35.0 cm³ of hydrochloric acid from 0.70 to 0.90 at 298 K. 

After a neutralisation reaction between sodium hydroxide and hydrochloric acid, a solution of sodium chloride is evaporated and 2.85 g of pure sodium chloride is produced. 

Determine the volume, in cm³, of 0.20 mol dm^-3 of hydrochloric acid required in the reaction to produce this mass of sodium chloride. 

44.00 cm³ of 0.20 mol dm^-3 hydrochloric acid is added to 40.00 cm³ of 0.50 mol dm^-3 sodium hydroxide. Calculate the pH of the resulting solution at 298 K. Give your answer to 2 decimal places.  

(K_w = 1.00 x 10^-14 mol² dm^-6 at 298 K)

25.00 cm³ of 0.20 mol dm^-3 barium hydroxide solution, Ba(OH)₂ (aq), is added to the 25.00 cm³ of 0.20 mol dm^-3 of hydrochloric acid. What is the pH of the new solution at 298 K? 

Give your answer to 2 decimal places.  

(K_w = 1.00 x 10^-14 mol² dm^-6 at 298 K)

Chemicals in the blood resist changes in pH when hydroxide ions enter the bloodstream.

Explain, using equations, how this occurs.

A buffer solution contains a mixture of ethanoic acid and its salt. A small amount of nitric acid is added to the buffer. 

Write an equation, including state symbols, showing how this buffer can resist the change in pH.

Determine the pH of the buffer solution which is 0.050 mol dm^-3 of ethanoic acid and 0.050 dm^-3 of sodium ethanoate. You must show working and give your answer to 2 decimal places. 

Calculate the concentration of methanoic acid used in a buffer which has a pH of 3.45 and a methanoate salt concentration of 0.149 mol dm^-3. Give your answer to 3 significant figures.

This question is about organic acids.

0.3825 g of an organic monobasic aromatic carboxylic acid containing only carbon, hydrogen and oxygen were dissolved in ethanol. A few drops of the indicator were added to the mixture titrated with 0.100 mol dm^-3 sodium hydroxide.

It took 25.50 cm³ of alkali to obtain the first permanent colour change.

Suggest a structure for the acid.

Table 1 shows a few common indicators and the pH ranges of their colour changes.

Suggest a suitable indicator from the table below for the procedure outlined in part (a) and explain your answer.

Table 1

The value of the acid dissociation constant, K_a, of benzoic acid is 6.3 x 10^-5 mol dm^-3 at 298K.

Calculate the pH of the 0.50 g dissolved in 250 cm³ of water. Give your answer to 2 decimal places. 

Calculate the pH of the solution formed when 0.060 g of sodium hydroxide is added to 500.00 cm³ of 0.005 mol dm^-3 of benzoic acid. Give your answer to 2 decimal places.

This question is about buffer solutions

What is the pH of a buffer solution made by dissolving 0.275 g of benzoic acid and 0.525 g of sodium benzoate in 250 cm³ of water? Give your answer to 2 decimal places. 

(K_a of benzoic acid = 6.3 x 10^-5 mol dm^-3)

Calculate the pH of a buffer solution made by mixing together 130 cm³ of 0.2 mol dm^-3 ethanoic acid and 85 cm³ of 0.45 mol dm^-3 sodium ethanoate. Give your answer to 2 decimal places.

Calculate the new pH of the buffer solution given in part (b) if 1.00 cm³ of 1.00 mol dm^-3 sodium hydroxide is added. Comment on the pH value after the addition of sodium

Buffers are solutions that can resist changes in pH if a small volume of acid or base is added.

This question is about pH titration curves.

Figure 1 shows a sketch of a graph pH curve when ammonia, NH₃ (aq), is added to a hydrochloric acid, HCl (aq). 

20.00 cm³ of 0.5 mol dm^-3 HCl (aq) was required to neutralise 38.65 cm³ of NH₃ (aq). 

Figure 1

[1]

The 'half volume method' can be used to find the K_a of a weak acid as pK_a = pH at the half equivalence point. This method was carried out as follows:

Step 1 15.00 cm³ of a weak acid was added to a conical flask with a few drops of phenolphthalein indicator.

Step 2 This solution was then titrated against NaOH (aq) until the endpoint.

Step 3 The volume of NaOH (aq) required to reach the endpoint was noted.

Step 4 The titration was then repeated without an indicator and adding only half the volume of NaOH (aq) required to reach the endpoint.

Step 5 The pH of the solution was measured using a pH probe.

The student’s graph is shown below in Figure 2.

Figure 2

Using Figure 2, calculate the value for K_a of the acid. Give your answer to 3 significant figures.

The complete neutralisation of sodium carbonate with hydrochloric acid happens in two separate stages. In the first stage, sodium hydrogencarbonate is produced. This then goes on to react further with hydrochloric acid in the second stage.

Figure 3 shows the change in pH during these two stages.

Explain using equations the two reactions in this double endpoint titration.

Figure 3

At 298K, water molecules dissociate into equal quantities of ions, and the pH is 7. 

The ionic product of water, K_w, can be used to find the pH of a strong base. Changing the temperature will affect the value for K_w.

At 40 ℃ the K_w of pure water is 2.916 x 10^-14 mol² dm^-3. 

Calculate the pH of pure water. Give your answer to 3 significant figures.

Strong bases fully ionise in water, as shown by the equation of dissociation of sodium hydroxide:

NaOH (aq) →  Na⁺ (aq) + OH^- (aq)

At 298K, K_w is 1 x 10^-14 mol² dm^-6. 

The ionic product of water, K_w is an equilibrium constant.

However, the expression for K_w does not include the concentration of water. Explain why.

Weak acids don’t fully ionise in solution. The equilibrium constant, K_a is used to determine the hydrogen ion concentration.

Write an expression for the acid dissociation constant, K_a for the acid HA. 

A sample of 0.01 mol dm^-3 butanoic acid has a K_a value of 1.51 x 10^-5 mol dm^-3.

The pH of a 0.15 mol dm^-3 solution of HCN is 5.08 at 298K. 

Determine the value of K_a for HCN at 298 K. 

Give your answer to two decimal place and state its units. 

The value of K_a can be used to determine the strength of an acid. The lower the value for K_a the weaker the acid is. Hydrofluoric acid has a K_a value of 5.5 x 10^-4. In comparison, the K_a value for ethanoic acid is 1.7 x 10^-5.

Considering the expression for K_a, explain why the value of K_a is larger in hydrofluoric acid than in ethanoic acid.

Formic acid is a weak monoprotic acid. At 298K the pH of 0.025 mol dm^-3 formic acid is 5.4.

Calculate the pK_a of formic acid at 298 K. Give your answer to three significant figures.

A student titrated 0.10 mol dm^-3 acid into a conical flask containing 25.0 cm³ of 0.1 mol dm^-3 of a base, recording the pH with each addition of acid.

The student repeated the procedure using different combinations of acids and bases. 

Identify which curve shown above, is the acid-base combination for the following: 

Identify which indicator given in the table would be most suitable for curve Y. Justify your answer. 

The pH curve shown below was obtained when a 0.150 mol dm^–3 solution of sodium hydroxide was added to 25.0 cm³ of an aqueous solution of ethanoic acid.

The half equivalence point is where half of the volume of sodium hydroxide required for neutralisation has been added to the ethanoic acid.

The student plotted a graph of the results of the reaction between butanoic acid and potassium hydroxide. The results are shown in the pH curve below.

Use the curve to determine the value of K_a for butanoic acid at 298K. State the units for K_a. 

This question is about buffers.

Give the meaning of the term buffer solution.

Buffers can be acidic but they can also be basic. This is determined by the reactants which are combined to create the buffer

Ethanoic acid is a weak acid. Hydrogen carbonate ions act as a weak acid if they are in an aqueous solution.

Explain how the solution of ethanoic acid works as a buffer when small amounts of alkali are added.

A buffer solution contains 0.10 mol dm^-3 concentration of methanoic acid and a 0.20 mol dm^-3 concentration of sodium methanoate. The values of K_a for methanoic acid is 1.80 × 10^–5 mol dm^–3. Calculate the pH of this buffer solution at 298 K. Give your answer to 2 decimal places.

Propanoic acid has an acid dissociation constant value, K_a, of 1.34 x 10^-5 mol dm⁻³ at 298K.

A buffer solution containing propanoic acid and sodium propanoate was prepared. 

The concentration of the propanoate ions in the buffer solution was 0.177 mol dm⁻³.  The pH of the buffer solution was 4.01. 

Give your answer to two decimal places.

This question is about buffers.

When we exercise, chemical changes occur which can cause our blood pH to drop. If the pH drops below 7.4 a condition called acidosis occurs. This can be very dangerous as many chemical reactions involve proteins which work at pH 7.4. The most important buffer for maintaining acid-base balance in the blood is the carbonic acid, H₂CO₃, hydrogencarbonate, HCO₃^- buffer.

Much of the atmospheric carbon dioxide we produce is absorbed by dissolving into the oceans, forming carbonic acid. An equilibrium is set up within the oceans using the same buffer solution as in the body, described in part (b). 

In this buffer solution there is an almost unlimited amount of hydrogen carbonate ions and the carbonic acid available has a high concentration.

Using your answer to (b) part (i), suggest the changes which would lead to more CO₂ dissolving into the oceans. Explain your answer.