Ethyl ethanoate is an ester.
One method for the formation of ethyl ethanoate is the reaction between ethanoland ethanoic acid, which is catalysed by hydrogen ions.
CH3COOH + C2H5OH ⇌ CH3COOC2H5 + H2O
An incomplete simplified mechanism for this reaction is shown.
(4)
The products of the esterification are
Justify your answer.
(2)
Include sign and units in your answer.
Quantity | Value |
Gas constant, R | 8.31 J mol−1 K−1 |
Temperature, T | 298 K |
Equilibrium constant of esterification reaction, K | 4.0 |
Enthalpy change of esterification reaction, ∆H | −6.0 kJ mol−1 |
Standard molar entropy of ethanoic acid, SO | 159.8 J K−1 mol−1 |
Standard molar entropy of ethanol, SO | 160.7 J K−1 mol−1 |
Standard molar entropy of water, SO | 69.9 J K−1mol−1 |
(6)
Ethyl ethanoate can also be formed by reacting ethanol with ethanoyl chloride, CH3COCl.
Identify three differences in the esterification reaction when ethanoyl chloride is used instead of ethanoic acid.
Did this page help you?