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Alkenes - Hydrohalogenation (DP IB Chemistry: HL)

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Hydrohalogenation of Alkenes

  • Alkenes will react readily with hydrogen halides such as HCl and HBr to produce halogenoalkanes
  • This reaction is known as hydrohalogenation 
  • It is also an electrophilic addition reaction that occurs quickly at room temperature

Hydrohalogenation reactions in alkenes

  • All the hydrogen halides react in this way, but the fastest reaction occurs in the order HI > HBr > HCl due to the increasing bond strength of the hydrogen-halogen bond, so the weakest bond reacts most easily
  • The mechanism of this reaction is part of Higher Level Chemistry and is covered in Section 20

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