AQA A Level Chemistry

Topic Questions

1.2 Formulae, Equations & Calculations

11 mark

Which is the correct definition of relative atomic mass?

  • the total mass of the subatomic particles in an atom

  • the mass of an atom compared to 1/12 the mass of a carbon-12 atom

  • the mass of an atom compared to the mass of a hydrogen-1 atom

  • the mass of a proton

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21 mark

What is the minimum volume of 0.5 mol dm-3 sulfuric acid needed to fully react with 2.43 g of magnesium powder?

Mg (s) + H2SO4 (aq) → MgSO4 (aq) + H2 (g)

  • 20 cm3

  • 50 cm3

  • 100 cm3

  • 200 cm3

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31 mark

When calcium carbonate is heated it decomposes according to the following equation

CaCO3 (s)  → CaO (s) +CO2 (g)

If 6.00 g of calcium carbonate is heated and produces 2.73 g of calcium oxide, what is the percentage yield of calcium oxide?

  • 81.25%

  • 81.18%

  • 123.19%

  • 123.08%

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41 mark

What are the correct smallest whole number coefficients to balance the chemical equation? 

__ Mg3N2 (s)  + __H2O (l) → __Mg(OH)2 (aq) + __NH3 (aq)

 

Mg3N2

H2O

Mg(OH)2

NH3

A

1

6

3

2

B

1

3

3

1

C

2

6

2

2

D

2

6

3

2

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51 mark

Hydrogen and chlorine react according to the following equation

                                          H2 (g)  + Cl2 (g) → 2HCl (g)

When 1.5 moles of chlorine reacts with 2.0 moles of hydrogen, what will be the result?

  • 3.5 mol of HCl

  • 1.5 mol of HCl and 0.5 mol of H2

  • 2.0 mol of HCl and 0.5 mol of Cl2

  • 3.0 mol of HCl and 0.5 mol of H2

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61 mark

A compound has an empirical formula of C2H6O and a molar mass of 92.0. What is the molecular formula of this compound?

  • C2H6O

  • C4H12O2

  • C6H18O3

  • C8H24O4

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71 mark

Which is the correct definition of relative molecular mass, Mr?

  • fraction numerator A v e r a g e space m a s s space o f space o n e space a t o m over denominator 1 divided by 12 space m a s s space o f space a n space a t o m space o f space to the power of 12 C end fraction

  • fraction numerator sum from blank to blank of space left parenthesis p e r c e n t a g e space i s o t o p e space a b u n d a n c e space cross times space i s o t o p e space m a s s space n u m b e r right parenthesis over denominator 100 end fraction

  • fraction numerator A v e r a g e space m a s s space o f space o n e space m o l e c u l e over denominator M a s s space o f space a n space a t o m space o f space to the power of 12 C end fraction

  • fraction numerator A v e r a g e space m a s s space o f space o n e space m o l e c u l e over denominator 1 divided by 12 space m a s s space o f space a n space a t o m space o f space to the power of 12 C end fraction

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81 mark

What is the relative molecular mass, Mr, of succinic acid?

9

  • 114 g mol-1

  • 116 g mol-1

  • 118 g mol-1

  • 120 g mol-1

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91 mark

A compound of copper and oxygen is shown to contain 88.8% copper and 11.2% oxygen by mass.

What is the correct empirical formula of the compound?

  • CuO

  • CuO2

  • Cu2O

  • Cu2O2

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11 mark

What is the whole number coefficient for oxygen when the equation for the combustion of pentanol is balanced?

C5H11OH (g)  +  O2 (g)  →  CO2 (g)  +  H2O (g)

  • 7

  • 8

  • 15

  • 16

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21 mark

A student reacted copper metal with excess sulfuric acid and collected 35.9 g of the hydrated copper sulfate crystals, CuSO45H2O crystals. The yield of crystals was 80.0%.

What was the original mass of copper used?

  • 7.3 g

  • 9.1 g

  • 11.4 g

  • 17.9 g

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31 mark

What is the empirical formula of an oxide of vanadium that contains 57.7% vanadium by mass?

  • VO2

  • V2O5

  • V3O7

  • V4O7

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41 mark

Magnesium sulfate can be made by the reaction of magnesium oxide with sulfuric acid

MgO + H2SO4 → MgSO4 + H2O

1.96 g of magnesium sulfate was produced in a reaction which had a percentage yield of 87.5%.

What mass of magnesium oxide, in mg, was used in the reaction?

  • 747

  • 750

  • 1247

  • 1.247

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51 mark

Which reaction has the highest atom economy for the production of the carbon containing product?

  • HCOOH (aq) + NH3 (aq) → HCONH2 (s) + H2O (l)

  • CH4 (g) + 2O2 (g) → 2H2O (g) + CO2 (g)

  • CH4 (g) + H2O (g) → 3H2 (g) + CO (g)

  • C (s) + 2H2O (g) → CO2 (g) + 2H2 (g)

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61 mark

4.900 g of a carbohydrate contains 2.063 g of carbon. The carbohydrate also contains 6.43% hydrogen by mass and the remainder of the carbohydrate is oxygen.

The relative molecular mass of the carbohydrate is 342 g mol-1.

What is the molecular formula of the carbohydrate?

  • CH2O

  • C10H30O12

  • C11H18O12

  • C12H22O11

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71 mark

A 250 cm3 solution was made by dissolving 3.56 g of Na2CO3nH2O in pure water.

26.70 cm3 of 0.150 mol dm-3 hydrochloric acid were required to neutralise a 25.0 cm3 of the solution.

What is the value of n in the Na2CO3nH2O?

  • 2

  • 4

  • 5

  • 7

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81 mark

In a thermal decomposition reaction, 6.27 g of calcium oxide is produced from calcium carbonate. The percentage conversion of calcium carbonate is 84.2%.

What mass of calcium carbonate underwent thermal decomposition? 

  • 9.0 g

  • 9.4 g

  • 11.2 g

  • 13.3 g

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91 mark

Aspirin is a common analgesic used for the relief of aches and pains.

13

Which row correctly describes aspirin?

 

Empirical formula

Molecular formula

Mr / g mol-1

A

C2H2O

C9H8O4 

180.0

B

C3H3O

C9H12O4 

184.0

C

C9H12O4 

C9H12O4 

184.0

D

C9H8O4 

C9H8O4 

180.0

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101 mark

Refer to the unbalanced equation below when answering this question.

2KMnO4 + 5H2C2O4 + _HCl → 2MnCl2 + _H2O + 10CO2 + 2KCl

In the balanced equation, the simplest mole ratio for hydrochloric acid to water is

  • 4 : 5

  • 3 : 4

  • 2 : 5

  • 1 : 2

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11 mark

The skeletal formula of limonene is shown.

qf1kQJGh_8

What is the empirical formula of limonene?

  • C10H16

  • C5H8

  • C10H12

  • C5H6

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21 mark

When heated magnesium carbonate, MgCO3, will decompose to a white solid and a gas, X.

6.90 g of anhydrous magnesium carbonate is heated until no further reaction takes place.

What is the mass of X produced?

  • 3.61 g

  • 7.20 g

  • 3.60 g

  • 1.80 g

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31 mark

2.12 g of a metal element reacts with 300 cm3 of oxygen at 298 K and 100 kPa, to form a metal oxide containing O2- ions.

The gas constant R = 8.31 J K–1 mol–1.

Identify the metal.

  • Magnesium

  • Calcium

  • Strontium

  • Barium

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41 mark

An additive in petrol is composed of lead, carbon and hydrogen only. The compound contains 64.11% lead and 29.7% carbon by mass.

What is the empirical formula of the additive?

  • PbC2H5

  • PbC8H20

  • Pb2C8H20

  • Pb2C16H40

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51 mark

A student completes a titration experiment to determine the percentage by mass of iron in steel wire.

Their titration results are shown in the table.

 

Rough

1

2

3

Initial volume / cm3 

0.00

0.15

11.95

7.00

Final volume / cm3 

24.35

24.60

36.70

33.50

Titre / cm3 

24.35

24.25

24.55

24.30

Calculate the mean titre.

  • 24.36 cm3

  • 24.30 cm3

  • 24.28 cm3

  • 24.37 cm3

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61 mark

15.0 g of a compound contains 6.105 g of carbon, 0.765 g of hydrogen and 8.130 g of oxygen. The relative molecular mass of the compound is 118.0 g mol-1.

What is the molecular formula of the compound?

  • C2H3O2

  • C4H8O4

  • CH1.5O

  • C4H6O4

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71 mark

Calcium carbonate undergoes thermal decomposition according to the following equation

CaCO3 (s)  → CaO (s) + CO2 (g)

If 6.00 g of calcium carbonate is heated and produces 2.73 g of calcium oxide, what is the percentage yield of calcium oxide?

  • 81.2%

  • 74.7%

  • 68.2%

  • 55.2%

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81 mark

The anti-cancer drug cisplatin has the chemical name dichlorodiamineplatinum (II). It is produced from a multi-step reaction. The first step in this reaction is shown in the following equation.

KPtCl4 + 4KI → KPtI4 + 4KCl

What is the percentage atom economy for the formation of the potassium tetraiodoplatinate (II), KPtI4, in this reaction?

  • 93.2%

  • 71.3%

  • 68.7%

  • 31.8%

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91 mark

A 13.81 g sample of magnesium sulphate, MgSO4.xH2O, was heated until no further change in mass was recorded. 6.75 g of the solid remained after strong heating.

What is the value of x?

  • 2

  • 5

  • 6

  • 7

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101 mark

A thermometer was used to measure the temperature change in a calorimetry experiment. 

The initial temperature was 19.0 degreeC and the final temperature was 26.5 degreeC.

Each reading of the thermometer has an uncertainty of ± 0.5 degreeC.

What is the percentage uncertainty in the temperature change?

  • 1.89%

  • 2.63%

  • 6.67%

  • 13.3%

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