CIE AS Chemistry

Revision Notes

Syllabus Edition

First teaching 2020

Last exams 2024

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1.3.16 Dot and Cross Diagrams

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Dot & Cross Diagrams

  • Dot and cross diagrams are diagrams that show the arrangement of the outer-shell electrons in an ionic or covalent compound or element
    • The electrons are shown as dots and crosses

  • In a dot and cross diagram:
    • Only the outer electrons are shown
    • The charge of the ion is spread evenly which is shown by using brackets
    • The charge on each ion is written at the top right-hand corner

Ionic compounds

  • Ionic bonds are formed when metal transfer electrons to a non-metal to form a positively charged and negatively charged ion
  • The atoms achieve a noble gas configuration

 

Chemical Bonding Ionic Dot & Cross, downloadable AS & A Level Chemistry revision notes

Dot-and-cross diagrams of ionic compounds in which one of the atoms transfers their valence electrons to the other

Covalent compounds

  • The atoms in covalent compounds will share their outer valence electrons to achieve a noble gas configuration

 Chemical Bonding Covalent Dot & Cross 1, downloadable AS & A Level Chemistry revision notesChemical Bonding Covalent Dot & Cross 2 (1), downloadable AS & A Level Chemistry revision notesChemical Bonding Covalent Dot & Cross 2 (2), downloadable AS & A Level Chemistry revision notesChemical Bonding Covalent Dot & Cross 3 (1), downloadable AS & A Level Chemistry revision notesChemical Bonding Covalent Dot & Cross 3 (2), downloadable AS & A Level Chemistry revision notes

Dot-and-cross diagrams of covalent compounds in which the atoms share their valence electrons

Coordinate bonding

  • Coordinate bonding or also called dative covalent bonding is formed when one atom provides both the electrons needed for a covalent bond
  • In a displayed formula, the dative covalent bond is represented by an arrow
  • The head of the arrow points away from the lone pair that forms the bond

 Chemical Bonding Dative Covalent Dot & Cross, downloadable AS & A Level Chemistry revision notes

Dot-and-cross diagrams of dative covalent compounds in which one of the atoms provides both the electrons in a covalent bond

Incomplete & expanded octet rule

  • Some species may contain more (expanded) or less (incomplete) than eight electrons in their outer shell

Chemical Bonding Expanded Covalent Dot & Cross (1), downloadable AS & A Level Chemistry revision notes Chemical Bonding Expanded Covalent Dot & Cross (2), downloadable AS & A Level Chemistry revision notes

Expanded octet rule

 Chemical Bonding Incomplete Covalent Dot & Cross, downloadable AS & A Level Chemistry revision notes

Incomplete octet rule

Odd number of electrons

  • Some atoms in compounds may have an odd number of electrons in their valence shell

 Chemical Bonding Odd Number of Electrons Dot & Cross, downloadable AS & A Level Chemistry revision notes

Incomplete octet rule

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Fran studied for a BSc in Chemistry with Forensic Science, and since graduating taught A level Chemistry in the UK for over 11 years. She studied for an MBA in Senior Leadership, and has held a number of roles during her time in Education, including Head of Chemistry, Head of Science and most recently as an Assistant Headteacher. In this role, she used her passion for education to drive improvement and success for staff and students across a number of subjects in addition to Science, supporting them to achieve their full potential. Fran has co-written Science textbooks, delivered CPD for teachers, and worked as an examiner for a number of UK exam boards.