CIE AS Chemistry

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Last exams 2024

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1.3.15 Inter & Intramolecular Forces

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Comparing Bonds to Intermolecular Forces

Intramolecular forces

  • Intramolecular forces are forces within a molecule
  • Ionic bonding is the electrostatic attraction between positive (cations) and negative (anions) ions in an ionic crystal lattice
    • These ions are formed by transferring the electrons from one species to the other

  • Covalent bonds are formed when the outer electrons of two atoms are shared
  • Metallic bonding is the electrostatic attraction of positively charged metal ions and their delocalised electrons in a metal lattice

Chemical Bonding Intramolecular Forces, downloadable AS & A Level Chemistry revision notes

Intramolecular forces

Intermolecular forces

  • Intermolecular forces are forces between molecules and are also called van der Waals’ forces
  • Permanent dipole - permanent dipole are the attractive forces between two neighbouring molecules with a permanent dipole
  • Hydrogen bonds are a special type of permanent dipole - permanent dipole forces
  • Instantaneous dipole - induced dipole (London dispersion) forces are the attractive forces between a temporary dipole and a neighbouring molecule with an induced dipole

Chemical Bonding Intermolecular Forces (1), downloadable AS & A Level Chemistry revision notes Chemical Bonding Intermolecular Forces (2), downloadable AS & A Level Chemistry revision notes Chemical Bonding Intermolecular Forces (3), downloadable AS & A Level Chemistry revision notes

Intermolecular forces

  • In general, the intramolecular forces are stronger than intermolecular forces
  • The strengths of the types of bond or force are as follows:

1-5-3-types-of-forces-between-molecules-new

The varying strengths of different types of bonds

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