Edexcel International A Level Chemistry

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1.9.1 Alkanes - Introduction

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Alkanes - Introduction

  • Hydrocarbons are compounds containing hydrogen and carbon only
  • Some of the hydrocarbon families that you are expected to know include: alkanes, alkenes and arenes
    • Alkanes and alkenes can be described as aliphatic
    • Arenes can be described as aromatic
  • Alkanes have the general molecular formula CnH2n+2 
  • They contain only single bonds and are said to be saturated
  • Alkanes are named using the nomenclature rule alk + ane
    • The alk portion of the name depends on the number of carbons
      • 1 carbon = meth
      • 2 carbons = eth
      • 3 carbons = prop
      • 4 carbons = but
      • 5 carbons = pent
      • After 5 carbons, the naming of alkanes matches the names of the polygons in Maths
    •  The ane portion of the name suggests single bonds between the carbon atoms

The First Six Members of the Alkane Family

  • Alkanes can be linear, branched or cyclic 
    • The key points are that there are no functional groups and only single bonds between the carbon atoms
  • Cycloalkanes have the general formula CnH2n
    • This general formula is the same as the alkene general formula but cycloalkanes are still saturated
    • Cycloalkanes are named using the nomenclature rule cyclo + alk + ane
      • The cyclo portion of the name shows that there is a ring stucture
      • As with alkanes, the alk portion of the name depends on the number of carbons
      •  The ane portion of the name suggests single bonds between the carbon atoms

An Introduction to AS Level Organic Chemistry Alkanes, downloadable AS & A Level Chemistry revision notes

Alkanes are compounds made up of carbon and hydrogen atoms only and contain no functional group

Alkanes - Reactions

  • The unreactive nature of alkanes can be explained by two factors
    • The high bond enthalpies of the C-C and C-H bonds
    • The very low polarity of the sigma (σ) bonds present

Bond enthalpy 

  • The C-C bond has a bond enthalpy of 316 kJ mol-1 and the C-H bond has a bond enthalpy of 411 kJ mol-1
  • The C-H bond is stronger as the bond length is less than the C-C bond
    • This is because the hydrogen atom only consists of one shell, so the distance between the nuclei is shorter 
    • Creating greater force of attraction to the nuclei and the pair of electron between them

Polarity

  • The electronegativities of carbon and hydrogen are very similar, therefore the bonds will have very low polarity 

Hydrocarbons Polarity Alkanes, downloadable AS & A Level Chemistry revision notes

Ethane is an example of an alkane that lacks polarity due to almost similar electronegativities of the carbon and hydrogen atoms

Alkanes are combusted (burnt) on a large scale for their use as fuels

Complete combustion

  • When alkanes are burnt in excess (plenty of) oxygen, complete combustion will take place and all carbon and hydrogen will be oxidised to carbon dioxide and water respectively
    • For example, the complete combustion of octane to carbon dioxide and water

Hydrocarbons Complete Combustion, downloadable AS & A Level Chemistry revision notes

The complete combustion of alkanes

Incomplete combustion

  • When alkanes are burnt in only a limited supply of oxygen, incomplete combustion will take place and not all the carbon is fully oxidised
  • Some carbon is only partially oxidised to form carbon monoxide
    • For example, the incomplete combustion of octane to form carbon monoxide

 Hydrocarbons Incomplete Combustion, downloadable AS & A Level Chemistry revision notes

The incomplete combustion of alkanes

  • Incomplete combustion often takes place inside a car engine due to a limited amount of oxygen present
  • With a reduced supply of oxygen, carbon will be produced in the form of soot:Incomplete Combustion of Alkanes, downloadable IB Chemistry revision notes

Free-radical substitution

  • Alkanes can undergo free-radical substitution in which a hydrogen atom gets substituted by a halogen (chlorine / bromine)
  • Since alkanes are very unreactive, ultraviolet light (sunlight) is needed for this substitution reaction to occur
  • The free-radical substitution reaction consists of three steps:
    • In the initiation step, the halogen bond (Cl-Cl or Br-Br) is broken by UV energy to form two radicals
    • These radicals create further radicals in a chain reaction called the propagation step
    • The reaction is terminated when two radicals collide with each other in a termination step

  • Alkanes can undergo free-radical substitution in which a hydrogen atom gets substituted by a halogen (chlorine/bromine)
    • Ultraviolet light (sunlight) is needed for this substitution reaction to occur

Hydrocarbons Colour Change of Solution, downloadable AS & A Level Chemistry revision notes

The fact that the bromine colour has disappeared only when mixed with an alkane and placed in sunlight suggests that the ultraviolet light is essential for the free radical substitution reaction to take place

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