Edexcel GCSE Chemistry

Topic Questions

6.2 Group 7

1a4 marks

The Group 7 elements exist in different states at room temperature.

Draw one straight line from each Group 7 element to its correct state at room temperature.

grouup-7-states

1b1 mark

Chlorine gas will react with sodium to form sodium chloride. 

Place a tick (✔) in the box which shows the type of bonding that exists in the compound sodium chloride:

 
 covalent bonding  
 ionic bonding  
 metallic bonding  
1c2 marks

When chlorine reacts with hydrogen, hydrogen chloride is formed.

Complete the dot and cross diagram in Figure 1 for hydrogen chloride.

hcl-dot-and-cross

Figure 1

1d2 marks

Use words from the box to complete the sentence about the reactivity of the halogens with hydrogen.

decreases less increases more


Reactivity ....................................... down Group 7, so iodine reacts ......................................... vigorously with hydrogen than chlorine.

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2a1 mark

This question is about Group 7 elements. 

Why are chlorine and bromine both in Group 7 of the Periodic Table?

2b2 marks

Here are four statements about Group 7 elements. 

Place ticks in boxes by the two statements that are correct. 

 Group 7 elements are known as noble gases   
 Group 7 elements are diatomic  
 Group 7 elements get less reactive going down the group   
 Group 7 elements react with metals to form covalent compounds   
2c1 mark

Bromine reacts with hydrogen to form hydrogen bromide. 

Suggest the pH of the solution that is formed when hydrogen bromide dissolves in water. 

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3a2 marks

Chlorine is an element found in Group 7 of the Periodic Table. 

Complete the dot and cross diagram for a chlorine molecule. 

You only need to show the outer electrons. 

screenshot-2024-02-28-093138

3b1 mark

Chlorine can take part in displacement reactions. 

What is meant by displacement?

3c2 marks

Complete the word equation for the displacement reaction between chlorine and potassium bromide. 

chlorine   +   potassium bromide   →   _________________   +  _________________

3d1 mark

Which statement about the reaction in part c) is correct?

  A A purple-black solid is produced
  B The solution produced is an orange-brown colour
  C A yellow gas is produced 
  D A yellow-green gas is produced

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4a2 marks

Fluorine is located at the top of Group 7 in the Periodic table. 

Write the electronic configuration of a:

i)
fluorine atom 

(1)

ii)
fluorine ion 
(1)

4b4 marks

Going down Group 7 the reactivity of the halogens decreases. 

Use words from the box to complete the sentences to explain why chlorine is less reactive than fluorine.

nucleus shells easier attraction
smaller harder greater distance

Chlorine has more _____________ than fluorine so the distance between the outer shell and the nucleus is _____________. 

Therefore there is less _____________ between the electron being gained and nucleus. 

This makes it ___________ to gain an electron.

4c1 mark

Chlorine reacts with sodium to form sodium chloride. 

What is the correct balanced equation for this reaction? 



A Na +  Cl →   NaCl 


B  Na2 +  2Cl →   2NaCl 


C 2Na  +  Cl→   2NaCl


D  Na  +  Cl2 →   NaCl
4d4 marks

Figure 1 shows five statements about the the reaction and substances involved in the reaction in part c). 

Put ticks in the boxes in Figure 1 to show which statements are true and which statements are false. 

The first one has been done for you. 

  true false
 sodium chloride is an ionic compound  
 sodium is an alkali metal     
 to test for chlorine a glowing splint will relight     
 the reaction is an example of displacement    
 chlorine is a poisonous gas    

Figure 1

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5a1 mark

Group 7 is an important family of elements in the Periodic Table.

Bromine is one element located here.

Give the number of electrons in the outer shell of a bromine atom. 

5b3 marks

The reactivity of Group 7 elements changes as you go down the group. 

Place the following Group 7 metals in order from least to most reactive.
 
  • bromine
  • fluorine
  • iodine
  • chlorine

least reactive            most reactive
_______________ _______________ _______________ _______________
5c3 marks

The melting points of the halogens changes going down the group. 

Use words from the box to complete the sentences.

increase stronger intermolecular
weaker covalent decrease

Going down Group 7 the melting points _______________ .

This is because the size of the molecules increases so the _______________  forces get _______________ .

5d2 marks

Describe how you would test for chlorine gas. 

You should give the result of this test.

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1a1 mark

The elements chlorine, bromine and iodine are part of group 7 in the periodic table.

The appearances of chlorine, bromine and iodine at room temperature are shown in Figure 10.

halogen appearance
chlorine green gas
bromine red-brown liquid
iodine grey solid


Figure 10


Astatine is the element below iodine in group 7.

Predict the appearance of astatine.

1b6 marks
The order of reactivity of chlorine, bromine and iodine can be determined by carrying out displacement reactions.

Explain how displacement reactions can be used to show the reactivity of these three elements.
1c
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6 marks

Higher Only

When iron wool is heated in bromine vapour, it reacts to form iron bromide.

i)

In an experiment, 5.60 g of iron reacted exactly with 24.0 g of bromine, Br2

[relative atomic masses: Fe = 56.0, Br = 80.0]
Determine, using this information, the balanced equation for the reaction between iron and bromine.
You must show your working.

(4)

ii)

When iron reacts with bromine, bromide ions are formed.

Explain the type of reaction bromine atoms undergo when they are converted to bromide ions.

(2)

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2a6 marks

Sodium thiosulfate solution, Na2S2O3, reacts with dilute hydrochloric acid.

Na2S2O3 (aq) + 2HCl (aq) → 2NaCl (aq) + H2O (l) + SO2 (g) + S (s)

i)
When dilute hydrochloric acid is mixed with sodium thiosulfate solution, the mixture turns cloudy.

Explain why the mixture turns cloudy.
(2)
ii)
In an investigation, different concentrations of hydrochloric acid are reacted with sodium thiosulfate solution.
The mixture goes cloudy at different rates.

Describe how the rate at which the mixture goes cloudy can be measured.
(3)
iii)
You are provided with some dilute hydrochloric acid which has a concentration of 50 g dm-3.

For this experiment, dilute hydrochloric acid with a concentration of 20 g dm-3 is required.

How much water must be added to 100 cm3 of 50 g dm-3 hydrochloric acid to make dilute hydrochloric acid with a concentration of 20 g dm-3?
(1)
  A 200 cm3
  B 150 cm3 
  C 100 cm3 
  D 50 cm3
2b3 marks

Higher Only

Sodium iodide solution is colourless.

When a solution of bromine is added to sodium iodide solution, a reaction occurs.

2NaI + Br2 → 2NaBr + I2

i)
The mixture turns brown.

Give the name of the substance causing the brown colour.
(1)
ii)
Explain which substance has been reduced in this reaction.
(2)

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3a2 marks

Describe what is seen when chlorine water is added to potassium bromide solution and the mixture shaken.

3b4 marks

Higher Only

Chlorine reacts with potassium bromide to form potassium chloride and bromine.

In this reaction chlorine forms chloride ions

Cl2 + 2KBr rightwards arrow 2KCl + Br

i)
In this reaction, chlorine has been reduced.
Explain, using the equation, how you know that chlorine has been reduced.
(2)
ii)
Write the half equation for the formation of bromine from bromide ions.
(2)
3c3 marks

Aluminium reacts with chlorine to form aluminium chloride.

Write the balanced equation for this reaction.

3d3 marks

A solid ionic compound is dissolved in water to form a solution.

Describe a simple experiment to show that charged particles are present in this solution.

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4a2 marks

Group 7 elements are known as the halogens. 

Chlorine is a Group 7 element with an atomic number of 17. 

Complete Figure 1 show the number of neutrons, protons and electrons in the two isotopes of chlorine. 

  chlorine-35 chlorine-37
number of neutrons    
number of protons    
number of electrons     

Figure 1

4b2 marks

A regular sample of chlorine contains only chlorine-37 and chlorine-35 atoms.

Explain why the relative atomic mass of chlorine is 35.5. 

4c2 marks

Chlorine can react with non-metals to form covalent compounds

It reacts with carbon to form tetrachloromethane, CCl4

Draw a dot and cross diagram to show the bonding in one molecule of this compound. 

Show outer shell electrons only. 

4d3 marks

Higher Only

Chlorine also reacts with potassium bromide in a displacement reaction. 

Cl2 + 2Kl  2KCl + l2

i)
Explain which species which has been reduced. 
(1)
ii)
Write the half equation for the oxidation reaction that occurs here. 
(2)

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5a1 mark

The elements in Group 7 are known as the halogens. 

Name the halogen in Period 5 of the Periodic Table.

5b3 marks

Explain why chlorine is more reactive than iodine.

5c1 mark

A piece of burning sodium is placed into a gas jar containing chlorine gas. 

This can be seen in Figure 1. 

White crystals can be seen coating the inside of the gas jar at the end of the reaction. 

Identify the white crystals. 

5d5 marks

Higher Only

Bromine is also located in Group 7. 

It can react with sodium. 

i)
Write the balanced equation for the reaction between bromine and sodium. 

(2)

ii)
A student adds sodium bromide solution to chlorine water.
State what you would see in this reaction. 

(1)

iii)
The ionic equation for the reaction between sodium bromide and chlorine is:

2Br + Cl2 → 2Cl+ Br2

Explain which species has been oxidised in this reaction.
(2) 

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11 mark

Astatine is found below iodine in Group 7 of the periodic table.

What is its formula and state at room temperature?

 
      Formula State at room temperature 
  A At gas
  B At solid
  C At2 liquid
  D At2 solid

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2a2 marks

A chlorine atom contains 17 electrons, 18 neutrons and 17 protons.

i)
State the mass number of this chlorine atom.
(1)
ii)
Give the electronic configuration of this chlorine atom.
(1)
2b2 marks

Describe what you would see if damp, blue litmus paper is placed into chlorine gas.

2c5 marks

Chlorine exists as diatomic molecules.
In a molecule, two chlorine atoms are joined by a covalent bond.

i)
Describe what is meant by a covalent bond.
(2)
ii)
Explain why chlorine is a gas, rather than a liquid, at room temperature.
(3)
2d1 mark

When the gas hydrogen chloride, HCl, is dissolved in water, a solution forms.
Blue litmus paper dipped in this solution turns red.

State why the litmus paper turns red.

2e2 marks
i)
Figure 13 lists the halogens in the order in which they appear in group 7 of the periodic table.

The melting points of four of the halogens are given.

halogen melting point in °C
fluorine −220
chlorine −101
bromine −7
iodine  
astatine 302

Figure 13

Estimate the melting point of iodine.

(1)

........................ °C

ii)
Bromine reacts with heated iron.

Give the name of one halogen that would react with iron more vigorously than bromine.

(1)

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31 mark

A student carried out a displacement reaction using an unknown halogen and a salt containing a halide ion.

As the reaction progressed they observed the formation of a dark brown solution.

Which halogen and salt did the students react together?  

 
  A Potassium iodide + bromine
  B Potassium bromide + chlorine
  C Potassium chloride + bromine
  D Potassium chloride + iodine

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41 mark

The boiling point of the halogens increases down Group 7.

Which statement explains why?

 
  A The covalent bonds get stronger going down the group and require more energy to overcome
  B The intermolecular forces get stronger going down the group and require more energy to overcome
  C The intermolecular forces get weaker going down the group and require less energy to overcome
  D The covalent bonds get weaker going down the group and require less energy to overcome

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5a2 marks
Complete the following sentences.

i)
The name given to group 7 in the periodic table is ............................................... .

(1)

ii)
The name given to group 0 in the periodic table is ............................................... .

(1)

5b1 mark

Which of the following rows gives the colours of the group 7 elements chlorine and bromine at room temperature?

 
      chlorine  bromine
  A red-brown  purple
  B yellow-green  grey
  C yellow-green  red-brown
  D grey  red-brown
5c1 mark

Figure 2 shows the melting and boiling points of bromine and iodine. 

element melting point in °C boiling point in °C
bromine –7 59
iodine 114 184
 
Figure 2
 

Using the information in Figure 2, which row shows the physical states of these elements at 50°C? 

 
    bromine iodine
A liquid  gas
B solid liquid
C gas  solid
D liquid  solid

5d
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1 mark

The densities of some elements in group 0 are shown in Figure 3.

name density in g cm–3
helium 0.15
neon 1.2
argon 1.4
krypton  
xenon 3.5
 
Figure 3

Use the information in Figure 3 to suggest the density of krypton.

5e2 marks
For many years, argon was used to fill filament light bulbs.
 

A filament light bulb is shown in Figure 4.

 
fig-4-q2e-1cho-2f-paper-1-june-2019
 
Figure 4
 

When the bulb is in use the metal filament becomes extremely hot. 

Explain why argon, rather than air, was used to fill filament light bulbs.

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61 mark

Higher Only

Chlorine reacts with potassium iodide to form potassium chloride and iodine. 

Cl2 (g)    +    2KI (aq)        →      2KCl (aq)     +     I(aq)

Which species has been reduced? 

 
  A Chlorine
  B Potassium
  C Potassium iodide
  D Potassium chloride 

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7a2 marks

Fluorine, chlorine, bromine, iodine and astatine are elements in group 7.

Describe the test to show that a gas is chlorine.

7b1 mark

Bromine reacts with hydrogen to form hydrogen bromide.
Hydrogen bromide dissolves in water to form a solution.

State the name of the solution formed.

7c2 marks

There is a trend in the colour and the state of the halogens at room temperature. 

Predict the colour and state of astatine at room temperature. 

 
colour ..............................
 
state ..............................
7d4 marks
Bromine, chlorine and iodine are dissolved in water to make aqueous solutions.
Potassium iodide solution is added to each of these solutions.

Figure 6 shows the observations.

halogen initial colour of aqueous solution final colour of mixture
  bromine   orange   brown
  chlorine   pale green   brown
  iodine   brown   brown

 

Figure 6

Explain the observations shown in the table.

7e2 marks

Fluorine reacts vigorously with iron to produce iron(III) fluoride, FeF3.

Write the balanced equation for this reaction.

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81 mark

Which test is used to confirm the presence of chlorine gas during a reaction?

 
  A Collect the gas and see if it extinguishes a glowing splint
  B Collect the gas and check if it is green
  C Collect the gas and see if it bleaches damp litmus paper
  D Collect the gas and check if it smells of swimming pools

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9a4 marks

Fluorine, chlorine, bromine and iodine are elements in group 7 of the periodic table.

i)
State the name given to the group 7 elements.

(1)

ii)
Name one other element that is in group 7.
Use the periodic table on the back of this exam paper to help you.

(1)

iii)
Which element is liquid at room temperature and pressure?

(1)

  A fluorine
  B chlorine 
  C bromine 
  D iodine 

iv)
Which element is dark-grey in colour at room temperature and pressure?

(1)

  A fluorine
  B chlorine 
  C bromine 
  D iodine 

9b
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3 marks
Tin reacts with chlorine to form tin chloride. A sample of tin chloride contains 1.19 g of tin and 1.42 g of chlorine.



Calculate the empirical formula of this tin chloride.
(relative atomic masses: Cl = 35.5, Sn = 119.0)
You must show your working.

9c2 marks

Tin also reacts with fluorine. The reaction between fluorine and tin is much more vigorous than the reaction between chlorine and tin.

Figure 8 shows the electronic configurations of fluorine and chlorine.

fig-8-q5c-1cho-2f-paper-1-nov-2021

Figure 8

Explain, in terms of their electronic configurations, why fluorine reacts with tin more vigorously than chlorine reacts with tin.

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101 mark

Bromine can react with hydrogen to form hydrogen bromide. 

Which statement is not true about hydrogen bromide? 

 
  A It is an acidic gas
  B It does not dissolve in water 
  C It contains covalent bonds
  D It is more stable than hydrogen iodide 

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11a1 mark

This question is about some of the elements in group 7 of the periodic table.

Which row in the table correctly shows the colours and physical states of the elements at room temperature?



  A iodine: purple gas bromine: yellow liquid
  B chlorine: pale green gas  iodine: brown solid
  C bromine: red-brown liquid  chlorine: yellow liquid
  D iodine: dark grey solid bromine: red-brown liquid
11b
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2 marks

The compound phosphorus oxychloride has the formula POCl3.

Calculate the percentage by mass of chlorine in phosphorus oxychloride.
(relative atomic masses: O = 16.0, P = 31.0, Cl = 35.5)

percentage by mass of chlorine = .......................................
11c
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3 marks

Higher Only

When iron reacts with chlorine, iron chloride is formed.

Two possible equations for this reaction are

A      Fe + Cl2→ FeCl2
    2Fe + 3Cl2→ 2FeCl3

In an experiment, 8.40 g iron reacts with chlorine to form 19.05 g iron chloride.


Show, using a calculation, which reaction, A or B, is taking place.
You must show your working.
(relative atomic masses: Cl = 35.5, Fe = 56.0)

11d6 marks
Group 1 metals react with the elements from group 7 to form salts.

Some examples of these reactions are shown in Figure 10.

reaction word equation
W lithium + chlorine → lithium chloride
X potassium + fluorine → potassium fluoride
Y rubidium + iodine → rubidium iodide
Z potassium + bromine → potassium bromide

Figure 10

You will find the position of these elements in their groups on the periodic table.

Explain, in terms of their electronic configurations and the relative reactivity of these elements, which of the reactions shown in Figure 10 would be the most violent.

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121 mark

A student adds some drops of bromine water to a solution of potassium iodide. 

Which statement is correct?

 
  A The solution turns brown
  B A yellow precipitate forms
  C The bromine water turns the solution orange
  D The bromine water decolourises the solution

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