Properties of Ionic Compounds (AQA GCSE Chemistry: Combined Science)

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Physical Properties of Ionic Compounds

  • Ionic compounds are made of charged particles called ions which form a giant lattice structure
  • Ionic substances have high melting and boiling points due to the presence of stronelectrostatic forces acting between the oppositely charged ions
  • These forces act in all directions and a lot of energy is required to overcome them
  • The greater the charge on the ions, the stronger the electrostatic forces and the higher the melting point will be
    • For example, magnesium oxide consists of Mg2+ and O2- so will have a higher melting point than sodium chloride which contains the ions, Na+ and Cl-

nacl-structures

Strong electrostatic forces act in all directions in an ionic solid such as sodium chloride

  • Ionic compounds are usually solid at room temperature and are non-volatile 
  • They are usually water soluble as both ionic compounds and water are polar substances

The Periodic Table - Hydration of Sodium Chloride, downloadable AS & A Level Chemistry revision notes

Ionic compounds are soluble in water because the ions are easily hydrated by polar water molecules

Exam Tip

Ions with higher charge have stronger electrostatic forces and will thus have higher melting and boiling points.

Electrical Conductivity: Ionic Compounds

  • For electrical current to flow there must be freely moving charged particles such as electrons or ions present 
  • Ionic compounds can conduct electricity in the molten state or in solution as they have ions that can move and carry charge
  • They cannot conduct electricity in the solid state as the ions are in fixed positions within the lattice and are unable to movemolten-ionic-substances-conduct-electricity-igcse-and-gcse-chemistry-revision-notes

Molten or aqueous particles move and conduct electricity but cannot in solid form

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Stewart

Author: Stewart

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.