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OCR A Level Chemistry

Revision Notes

Home / A Level / Chemistry / OCR / Revision Notes / 3. Periodic Table & Energy / 3.5 Reaction Rates / 3.5.2 Catalysis


3.5.2 Catalysis


The Role of a Catalyst

  • A catalyst is a substance that increases the rate of reaction without taking part in the chemical reaction by providing the particles an alternative mechanism with a lower activation energyReaction Kinetics Catalyst Reaction Pathway, downloadable AS & A Level Chemistry revision notes

A catalyst increases the rate of a reaction by providing an alternative pathway which has a lower activation energy

Importance of Catalysts

  • Catalysts can be divided into two types:
    • Homogeneous catalysts
    • Heterogeneous catalysts

  • Homogeneous means that the catalyst is in the same phase as the reactants
    • For example, the reactants and the catalysts are all in solution

  • Heterogeneous means that the catalyst is in a different phase to the reactants
    • For example, the reactants are gases, but the catalyst used is a solid

Benefits of catalysts

  • Catalysts speed up the rate of reaction, meaning the use of a catalyst may mean lower temperatures and pressures can be used
    • This can save energy costs as there is reduced energy demand for providing high temperatures and less electrical pumping costs for producing the high pressures usually required
    • This can mean fewer CO2 emissions from burning fossil fuels
  • Catalysts can also enable different reactions to be used, with better atom economy and with reduced waste, or fewer undesired products or less use of hazardous solvents and reactants
  • Catalysts are often enzymes, generating very specific products, and operating effectively close to room temperature and pressure



  • 1. Development of Practical Skills in Chemistry
    • 1.1 Physical Chemistry Practicals
      • 1.1.1 Moles Determination
        • 1.1.2 Acid-Base Titration
          • 1.1.3 Determination of Enthalpy Changes
          • 1.2 Organic & Inorganic Practicals
            • 1.2.1 Qualitative Analysis of Ions
              • 1.2.2 Synthesis of a Haloalkane
                • 1.2.3 Preparation of Cyclohexene
                  • 1.2.4 Oxidation of Ethanol
                  • 1.3 Further Organic & Inorganic Chemistry Practicals
                    • 1.3.1 Synthesis of Aspirin
                      • 1.3.2 Preparation of Benzoic Acid
                        • 1.3.3 Preparation of Methyl 3-Nitrobenzoate
                          • 1.3.4 Qualitative Analysis of Organic Functional Groups
                            • 1.3.5 Electrochemical Cells
                            • 1.4 Further Physical Chemistry Practicals
                              • 1.4.1 Reaction - Magnesium & Hydrochloric Acid
                                • 1.4.2 Rates – Iodine Clock
                                  • 1.4.3 pH – Titration Curves
                                • 2. Foundations in Chemistry
                                  • 2.1 Atoms & Reactions
                                    • 2.1.1 Atomic Structure & Isotopes
                                      • 2.1.2 Atomic Structure & Mass Spectrometry
                                        • 2.1.3 Compounds, Formulae & Equations
                                        • 2.2 Amount of Substance
                                          • 2.2.1 Amount of Substance
                                            • 2.2.2 Determining Formulae
                                              • 2.2.3 Reaction Calculations
                                                • 2.2.4 The Ideal Gas Equation
                                                  • 2.2.5 Percentage Yield & Atom Economy
                                                  • 2.3 Acid-base & Redox Reactions
                                                    • 2.3.1 Acids
                                                      • 2.3.2 Acid-base Titrations
                                                        • 2.3.3 Redox
                                                        • 2.4 Electrons, Bonding & Structure
                                                          • 2.4.1 Electron Structure
                                                            • 2.4.2 Ionic Bonding & Structure
                                                              • 2.4.3 Covalent Bonding & Structure
                                                              • 2.5 The Shapes of Simple Molecules & Ions
                                                                • 2.5.1 The Shapes of Simple Molecules & Ions
                                                                  • 2.5.2 Electronegativity & Bond Polarity
                                                                    • 2.5.3 Intermolecular Forces
                                                                  • 3. Periodic Table & Energy
                                                                    • 3.1 Periodicity
                                                                      • 3.1.1 Periodicity
                                                                        • 3.1.2 Ionisation Energy
                                                                          • 3.1.3 Structure & Physical Properties
                                                                          • 3.2 Group 2
                                                                            • 3.2.1 Group 2 Elements
                                                                              • 3.2.2 Group 2 Compounds
                                                                              • 3.3 The Halogens
                                                                                • 3.3.1 The Halogens
                                                                                  • 3.3.2 Uses of Chlorine
                                                                                    • 3.3.3 Qualitative Analysis
                                                                                    • 3.4 Enthalpy Changes
                                                                                      • 3.4.1 Enthalpy Changes
                                                                                        • 3.4.2 Calorimetry
                                                                                          • 3.4.3 Bond Enthalpies
                                                                                            • 3.4.4 Hess' Law
                                                                                            • 3.5 Reaction Rates
                                                                                              • 3.5.1 Simple Collision Theory
                                                                                                • 3.5.2 Catalysis
                                                                                                  • 3.5.3 The Boltzmann Distribution
                                                                                                  • 3.6 Chemical Equilibrium
                                                                                                    • 3.6.1 Dynamic Equilibrium
                                                                                                      • 3.6.2 Le Chatelier’s Principle
                                                                                                        • 3.6.3 The Equilibrium Constant, Kc
                                                                                                      • 4. Core Organic Chemistry
                                                                                                        • 4.1 Basic Concepts
                                                                                                          • 4.1.1 Chemical Names & Formulae
                                                                                                            • 4.1.2 Functional Groups
                                                                                                              • 4.1.3 Structural Isomerism
                                                                                                                • 4.1.4 Reaction Mechanisms
                                                                                                                • 4.2 Alkanes
                                                                                                                  • 4.2.1 Introduction to Alkanes
                                                                                                                    • 4.2.2 Reactions of Alkanes
                                                                                                                      • 4.2.3 Free Radical Substitution of Alkanes
                                                                                                                      • 4.3 Alkenes
                                                                                                                        • 4.3.1 Introduction to Alkenes
                                                                                                                          • 4.3.2 Stereoisomerism in Alkenes
                                                                                                                            • 4.3.3 Addition Reactions of Alkenes
                                                                                                                              • 4.3.4 Electrophilic Addition
                                                                                                                                • 4.3.5 Polymers from Alkenes
                                                                                                                                • 4.4 Alcohols
                                                                                                                                  • 4.4.1 Properties of Alcohols
                                                                                                                                    • 4.4.2 Reactions of Alcohols
                                                                                                                                    • 4.5 Haloalkanes
                                                                                                                                      • 4.5.1 Reactions of Haloalkanes
                                                                                                                                        • 4.5.2 Nucleophilic Substitution of Haloalkanes
                                                                                                                                          • 4.5.3 Hydrolysis of Primary Haloalkanes
                                                                                                                                            • 4.5.4 Environmental Concerns of Organohalogen Use
                                                                                                                                            • 4.6 Organic Synthesis
                                                                                                                                              • 4.6.1 Techniques
                                                                                                                                                • 4.6.2 Synthetic Routes
                                                                                                                                                • 4.7 Analytical Techniques
                                                                                                                                                  • 4.7.1 Infrared Spectroscopy
                                                                                                                                                    • 4.7.2 Mass Spectrometry
                                                                                                                                                      • 4.7.3 Combined Techniques
                                                                                                                                                    • 5. Physical Chemistry & Transition Elements (A Level Only)
                                                                                                                                                      • 5.1 Rates, Orders & Arrhenius
                                                                                                                                                        • 5.1.1 Rates & Orders
                                                                                                                                                          • 5.1.2 Concentration-Time Graphs
                                                                                                                                                            • 5.1.3 Rate-Concentration Graphs
                                                                                                                                                              • 5.1.4 Investigating Reaction Rates
                                                                                                                                                                • 5.1.5 Rate-determining Step
                                                                                                                                                                  • 5.1.6 Temperature & Rate Constants
                                                                                                                                                                    • 5.1.7 The Arrhenius Equation
                                                                                                                                                                    • 5.2 Equilibria
                                                                                                                                                                      • 5.2.1 Equilibrium Terms
                                                                                                                                                                        • 5.2.2 Kc & Kp
                                                                                                                                                                          • 5.2.3 Equilibrium Constants & Changing Conditions
                                                                                                                                                                          • 5.3 Acids, Bases & Buffers
                                                                                                                                                                            • 5.3.1 Acids & Bases
                                                                                                                                                                              • 5.3.2 Ka, pH & Kw
                                                                                                                                                                                • 5.3.3 pH Calculations
                                                                                                                                                                                  • 5.3.4 Buffers
                                                                                                                                                                                    • 5.3.5 Neutralisation
                                                                                                                                                                                    • 5.4 Thermodynamics
                                                                                                                                                                                      • 5.4.1 Lattice Enthalpy
                                                                                                                                                                                        • 5.4.2 Building Born-Haber Cycles
                                                                                                                                                                                          • 5.4.3 Calculations Using Born-Haber Cycles
                                                                                                                                                                                            • 5.4.4 Enthalpy of Solution & Hydration
                                                                                                                                                                                              • 5.4.5 The Effect of Ionic Charge & Radius on Enthalpy
                                                                                                                                                                                                • 5.4.6 Entropy
                                                                                                                                                                                                  • 5.4.7 The Feasibillity of a Reaction
                                                                                                                                                                                                    • 5.4.8 Gibbs Free Energy, ΔG
                                                                                                                                                                                                    • 5.5 Redox & Electrochemistry
                                                                                                                                                                                                      • 5.5.1 Redox
                                                                                                                                                                                                        • 5.5.2 Redox Titrations
                                                                                                                                                                                                          • 5.5.3 Electrode Potentials
                                                                                                                                                                                                            • 5.5.4 Electrode Potential Calculations
                                                                                                                                                                                                              • 5.5.5 Cells
                                                                                                                                                                                                              • 5.6 Transition Elements
                                                                                                                                                                                                                • 5.6.1 Transition Elements
                                                                                                                                                                                                                  • 5.6.2 Ligands & Complex Ions
                                                                                                                                                                                                                    • 5.6.3 Isomerism in Transition Element Complexes
                                                                                                                                                                                                                      • 5.6.4 Ligand Substitution Reactions
                                                                                                                                                                                                                        • 5.6.5 The Biochemical Importance of Iron in Haemoglobin
                                                                                                                                                                                                                          • 5.6.6 Redox Reactions of Transistion Elements
                                                                                                                                                                                                                            • 5.6.7 Qualitative Analysis
                                                                                                                                                                                                                          • 6. Organic Chemistry & Analysis (A Level Only)
                                                                                                                                                                                                                            • 6.1 Benzene & Aromatic Compounds
                                                                                                                                                                                                                              • 6.1.1 Benzene
                                                                                                                                                                                                                                • 6.1.2 Electrophilic Substitution
                                                                                                                                                                                                                                  • 6.1.3 Phenol
                                                                                                                                                                                                                                    • 6.1.4 Directing Effects
                                                                                                                                                                                                                                    • 6.2 Carbonyl Compounds
                                                                                                                                                                                                                                      • 6.2.1 Reactions of Carbonyl Compounds
                                                                                                                                                                                                                                        • 6.2.2 Testing for Carbonyl Compounds
                                                                                                                                                                                                                                        • 6.3 Carboxylic Acids & Esters
                                                                                                                                                                                                                                          • 6.3.1 Carboxylic Acids
                                                                                                                                                                                                                                            • 6.3.2 Esters
                                                                                                                                                                                                                                              • 6.3.3 Acyl Chlorides
                                                                                                                                                                                                                                              • 6.4 Nitrogen Compounds
                                                                                                                                                                                                                                                • 6.4.1 Amines
                                                                                                                                                                                                                                                  • 6.4.2 Preparing Amines
                                                                                                                                                                                                                                                    • 6.4.3 Amino acids
                                                                                                                                                                                                                                                      • 6.4.4 Amides
                                                                                                                                                                                                                                                      • 6.5 Optical Isomerism
                                                                                                                                                                                                                                                        • 6.5.1 Optical Isomers
                                                                                                                                                                                                                                                          • 6.5.2 Identification of Chiral Centres
                                                                                                                                                                                                                                                          • 6.6 Polymers
                                                                                                                                                                                                                                                            • 6.6.1 Condensation Polymers
                                                                                                                                                                                                                                                              • 6.6.2 Polymer Repeat Units
                                                                                                                                                                                                                                                              • 6.7 Extending Carbon Chains
                                                                                                                                                                                                                                                                • 6.7.1 Nitriles
                                                                                                                                                                                                                                                                  • 6.7.2 Substituted Aromatic Carbon-carbon Bond Formation
                                                                                                                                                                                                                                                                  • 6.8 Organic Synthesis
                                                                                                                                                                                                                                                                    • 6.8.1 Techniques
                                                                                                                                                                                                                                                                      • 6.8.2 Synthetic Routes
                                                                                                                                                                                                                                                                      • 6.9 Analytical Techniques
                                                                                                                                                                                                                                                                        • 6.9.1 Thin Layer Chromatography, TLC
                                                                                                                                                                                                                                                                          • 6.9.2 Gas Chromatography, GC
                                                                                                                                                                                                                                                                            • 6.9.3 Qualitative Analysis
                                                                                                                                                                                                                                                                              • 6.9.4 Carbon-13 NMR
                                                                                                                                                                                                                                                                                • 6.9.5 Proton NMR
                                                                                                                                                                                                                                                                                  • 6.9.6 Combined Techniques


                                                                                                                                                                                                                                                                                  DOWNLOAD PDF

                                                                                                                                                                                                                                                                                Author: Sonny



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