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Edexcel A Level Chemistry

Revision Notes

Home / A Level / Chemistry / Edexcel / Revision Notes / 1. Physical Chemistry / 1.6 Formulae, Equations & Avogadro / 1.6.5 Amount of Substance Calculations


1.6.5 Amount of Substance Calculations


Amount of Substance Calculations

  • As previously discussed, the amount of substance can be defined as the number of particles in a substance, n, measured in moles (often abbreviated to mol)
  • In reality, amount of substance is used as a blanket term to cover most chemical calculations, especially those that involve moles
  • The two main calculations for amount of substance are:

Moles, n = fraction numerator m a s s comma space m over denominator m o l a r space m a s s comma space M end fraction

Moles, n = concentration x volume

  • Other common calculations for amount of substance include:

Moles, n = fraction numerator n u m b e r space o f space p a r t i c l e s over denominator A v o g a d r o apostrophe s space c o n s t a n t end fraction

Moles, n =fraction numerator P V over denominator R T end fractionfrom the ideal gas equation (PV = nRT)

Reacting Mass Calculations

  • Chemical equations can be used to calculate the moles or masses of reactants and products
  • To do this, information given in the question is used to find the amount in moles of the substances being considered
  • Then, the ratio between the substances is identified using the balanced chemical equation
  • Once the moles have been determined they can then be converted into grams using the relative atomic or relative formula masses

Worked Example

Example 1

Calculate the mass of magnesium oxide that can be made by completely burning 6.0 g of magnesium in oxygen in the following reaction:

2Mg (s) + O2 (g)  ⟶ 2 MgO (s) 

Answer

Reacting Masses WE 1, downloadable IGCSE & GCSE Chemistry revision notes

Worked Example

Example 2

Calculate the mass of aluminium, in tonnes, that can be produced from 51 tonnes of aluminium oxide. The equation for the reaction is:

2Al2O3  ⟶  4Al +  3O2 

Answer

Reacting Masses WE 2 2, downloadable IGCSE & GCSE Chemistry revision notes

Exam Tip

As long as you are consistent it doesn't matter whether you work in grams or tonnes or any other mass unit as the reacting masses will always be in proportion to the balanced equation.

Balancing Equations using Reacting Masses

  • If the masses of reactants and products of a reaction are known then we can use them to write a balanced equation for that reaction
  • This is done by converting the masses to moles and simplifying to find the molar ratios

Worked Example

Example 3

A student reacts 1.2 g of carbon with 16.2 g of zinc oxide. The resulting products are 4.4 g of carbon dioxide and 13 g of zinc. Determine the balanced equation for the reaction.

Answer

Balancing Equations from Reacting Masses WE 1, downloadable IGCSE & GCSE Chemistry revision notesBalancing Equations from Reacting Masses WE 2, downloadable IGCSE & GCSE Chemistry revision notes

Exam Tip

These questions look hard but they are actually quite easy to do, as long as you follow the steps and organise your work neatly.

Remember the molar ratio of a balanced equation gives you the ratio of the amounts of each substance in the reaction.



  • 1. Physical Chemistry
    • 1.1 Atomic Structure
      • 1.1.1 Structure of the Atom
        • 1.1.2 Isotopes
          • 1.1.3 Relative Mass
            • 1.1.4 Mass Spectrometry
            • 1.2 Ions & Electrons
              • 1.2.1 Ionisation Energy
                • 1.2.2 Quantum Shells
                  • 1.2.3 Orbitals
                    • 1.2.4 Electronic Configurations
                    • 1.3 The Periodic Table
                      • 1.3.1 Periodicity
                      • 1.4 Bonding
                        • 1.4.1 Ionic Bonding Overview
                          • 1.4.2 Representing Ionic Bonding
                            • 1.4.3 Ionic Trends
                              • 1.4.4 Physical Properties of Ionic Compounds
                                • 1.4.5 Covalent Bonding Overview
                                  • 1.4.6 Covalent Dot-and-Cross Diagrams
                                    • 1.4.7 Bond Length & Bond Strength
                                      • 1.4.8 Shapes of Covalent Compounds
                                      • 1.5 Structure
                                        • 1.5.1 Electronegativity
                                          • 1.5.2 Intermolecular Forces
                                            • 1.5.3 Hydrogen Bonding
                                              • 1.5.4 Intermolecular Forces & Physical Properties
                                                • 1.5.5 Metallic Bonding
                                                  • 1.5.6 Giant Lattices
                                                    • 1.5.7 Covalent Structures
                                                      • 1.5.8 Predicting Structures
                                                      • 1.6 Formulae, Equations & Avogadro
                                                        • 1.6.1 Empirical & Molecular Formulae
                                                          • 1.6.2 Balanced Equations
                                                            • 1.6.3 Applying Equations
                                                              • 1.6.4 The Mole & the Avogadro Constant
                                                                • 1.6.5 Amount of Substance Calculations
                                                                • 1.7 Reaction Calculations
                                                                  • 1.7.1 Reacting Volume Calculations
                                                                    • 1.7.2 Titrations
                                                                      • 1.7.3 Error & Uncertainty
                                                                        • 1.7.4 Yield & Atom Economy
                                                                        • 1.8 Energetics I
                                                                          • 1.8.1 Enthalpy Changes
                                                                            • 1.8.2 Enthalpy Level Diagrams
                                                                              • 1.8.3 Calorimetry
                                                                                • 1.8.4 Hess Cycles
                                                                                  • 1.8.5 Bond Enthalpy
                                                                                  • 1.9 Kinetics I
                                                                                    • 1.9.1 Collision Theory & Rates
                                                                                      • 1.9.2 Calculating Rates of Reaction
                                                                                        • 1.9.3 Maxwell-Boltzmann Distributions
                                                                                          • 1.9.4 Catalysts in Industry
                                                                                          • 1.10 Equilibrium I
                                                                                            • 1.10.1 Dynamic Equilibrium
                                                                                              • 1.10.2 Le Chatelier's Principle
                                                                                                • 1.10.3 The Rate & Yield Compromise
                                                                                                  • 1.10.4 Deducing Kc Expressions
                                                                                                • 2. Inorganic Chemistry
                                                                                                  • 2.1 Redox I
                                                                                                    • 2.1.1 Oxidation Number
                                                                                                      • 2.1.2 Types of Reduction & Oxidation
                                                                                                        • 2.1.3 Redox & Disproportionation
                                                                                                          • 2.1.4 Ionic Equations
                                                                                                          • 2.2 Groups 1 & 2
                                                                                                            • 2.2.1 Explaining Group 2 Trends
                                                                                                              • 2.2.2 Reactions of Group 2
                                                                                                                • 2.2.3 Group 2 Hydroxides & Sulfates
                                                                                                                  • 2.2.4 Group 2 Carbonates & Nitrates
                                                                                                                    • 2.2.5 Flame Tests
                                                                                                                    • 2.3 Group 7
                                                                                                                      • 2.3.1 Group 7 Trends
                                                                                                                        • 2.3.2 Halogen Displacement Reactions
                                                                                                                          • 2.3.3 Halogen Redox Reactions
                                                                                                                            • 2.3.4 Halide Ion Reactions
                                                                                                                          • 3. Organic Chemistry
                                                                                                                            • 3.1 Introduction to Organic Chemistry
                                                                                                                              • 3.1.1 Formulae of Organic Compounds
                                                                                                                                • 3.1.2 Homologous Series & Functional Groups
                                                                                                                                  • 3.1.3 Nomenclature & Classification
                                                                                                                                    • 3.1.4 Structural Isomerism
                                                                                                                                      • 3.1.5 Stereoisomerism
                                                                                                                                      • 3.2 Alkanes
                                                                                                                                        • 3.2.1 Describing Alkanes
                                                                                                                                          • 3.2.2 Alkane Fuels
                                                                                                                                            • 3.2.3 Pollution from Combustion
                                                                                                                                              • 3.2.4 Reducing Pollution
                                                                                                                                                • 3.2.5 Free Radicals
                                                                                                                                                • 3.3 Alkenes
                                                                                                                                                  • 3.3.1 Describing Alkenes
                                                                                                                                                    • 3.3.2 Bonding in Alkenes
                                                                                                                                                      • 3.3.3 Electrophilic Addition
                                                                                                                                                        • 3.3.4 Electrophilic Addition Mechanism
                                                                                                                                                          • 3.3.5 Saturation Test
                                                                                                                                                            • 3.3.6 Addition Polymerisation
                                                                                                                                                              • 3.3.7 Waste Polymers
                                                                                                                                                              • 3.4 Halogenoalkanes
                                                                                                                                                                • 3.4.1 Classifying Halogenoalkanes
                                                                                                                                                                  • 3.4.2 Nucleophilic Substitution
                                                                                                                                                                    • 3.4.3 Nucleophilic Substitution Mechanism
                                                                                                                                                                      • 3.4.4 Hydrolysis of Halogenoalkanes
                                                                                                                                                                        • 3.4.5 Reactivity of Halogenoalkanes
                                                                                                                                                                        • 3.5 Alcohols
                                                                                                                                                                          • 3.5.1 Classifying Alcohols
                                                                                                                                                                            • 3.5.2 Reactions of Alcohols
                                                                                                                                                                              • 3.5.3 Organic Liquid Preparation & Purification
                                                                                                                                                                              • 3.6 Modern Analytical Techniques I
                                                                                                                                                                                • 3.6.1 Mass Spectrometry
                                                                                                                                                                                  • 3.6.2 Infrared (IR) Spectroscopy
                                                                                                                                                                                • 4. Core Chemistry Practicals
                                                                                                                                                                                  • 4.1 Physical Chemistry Core Practicals
                                                                                                                                                                                    • 4.1.1 Molar Volume of a Gas
                                                                                                                                                                                      • 4.1.2 Standard Solutions
                                                                                                                                                                                        • 4.1.3 Determining Concentrations
                                                                                                                                                                                          • 4.1.4 Determining Enthalpy Change of Reaction
                                                                                                                                                                                          • 4.2 Inorganic & Organic Chemistry Core Practicals
                                                                                                                                                                                            • 4.2.1 Hydrolysis of Halogenoalkanes
                                                                                                                                                                                              • 4.2.2 Ethanol Oxidation
                                                                                                                                                                                                • 4.2.3 Chlorination of 2-Methylpropan-2-ol
                                                                                                                                                                                                  • 4.2.4 Qualitative Analysis
                                                                                                                                                                                                • 5. Advanced Physical Chemistry (A Level Only)
                                                                                                                                                                                                  • 5.1 Equilibrium II
                                                                                                                                                                                                    • 5.1.1 Deducing Kp Expressions
                                                                                                                                                                                                      • 5.1.2 Equilbrium Constant Calculations
                                                                                                                                                                                                        • 5.1.3 Reaction Conditions & The Equilibrium Constant
                                                                                                                                                                                                        • 5.2 Acid-base Equilibria
                                                                                                                                                                                                          • 5.2.1 Brønsted–Lowry Acids & Bases
                                                                                                                                                                                                            • 5.2.2 pH
                                                                                                                                                                                                              • 5.2.3 Acid Strength
                                                                                                                                                                                                                • 5.2.4 Ionic Product of Water
                                                                                                                                                                                                                  • 5.2.5 Measuring and Comparing pH
                                                                                                                                                                                                                    • 5.2.6 Titration Curves
                                                                                                                                                                                                                      • 5.2.7 Buffers
                                                                                                                                                                                                                        • 5.2.8 Weak Acid - Strong Base Titration
                                                                                                                                                                                                                        • 5.3 Energetics II: Born-Haber
                                                                                                                                                                                                                          • 5.3.1 Lattice Energy
                                                                                                                                                                                                                            • 5.3.2 Born-Haber Cycles
                                                                                                                                                                                                                              • 5.3.3 Polarising Power
                                                                                                                                                                                                                                • 5.3.4 Enthalpy of Solution
                                                                                                                                                                                                                                • 5.4 Energetics II: Entropy
                                                                                                                                                                                                                                  • 5.4.1 Introducing Entropy
                                                                                                                                                                                                                                    • 5.4.2 Entropy Calculations
                                                                                                                                                                                                                                      • 5.4.3 Gibbs Free Energy
                                                                                                                                                                                                                                        • 5.4.4 Feasible Reactions
                                                                                                                                                                                                                                        • 5.5 Kinetics II
                                                                                                                                                                                                                                          • 5.5.1 Rates of Reaction
                                                                                                                                                                                                                                            • 5.5.2 Rate Equations
                                                                                                                                                                                                                                              • 5.5.3 Rates - Experimental Techniques
                                                                                                                                                                                                                                                • 5.5.4 Initial Rates Method
                                                                                                                                                                                                                                                  • 5.5.5 Continuous Monitoring Method
                                                                                                                                                                                                                                                    • 5.5.6 Reaction Order Graphs
                                                                                                                                                                                                                                                      • 5.5.7 Rate-Determining Steps
                                                                                                                                                                                                                                                        • 5.5.8 Rates & Reaction Mechanisms
                                                                                                                                                                                                                                                          • 5.5.9 Arrhenius & Activation Energy
                                                                                                                                                                                                                                                        • 6. Advanced Inorganic Chemistry (A Level Only)
                                                                                                                                                                                                                                                          • 6.1 Redox II
                                                                                                                                                                                                                                                            • 6.1.1 Reduction & Oxidation
                                                                                                                                                                                                                                                              • 6.1.2 Standard Electrode Potential
                                                                                                                                                                                                                                                                • 6.1.3 Measuring Standard Electrode Potential
                                                                                                                                                                                                                                                                  • 6.1.4 Conventional Cell Representation
                                                                                                                                                                                                                                                                    • 6.1.5 Thermodynamics & Electrode Potential
                                                                                                                                                                                                                                                                      • 6.1.6 Disproportionation & Electrode Potential
                                                                                                                                                                                                                                                                        • 6.1.7 Storage Cells
                                                                                                                                                                                                                                                                          • 6.1.8 Fuel Cells
                                                                                                                                                                                                                                                                            • 6.1.9 Redox Titration Calculations
                                                                                                                                                                                                                                                                            • 6.2 Principles of Transition Metal Chemistry
                                                                                                                                                                                                                                                                              • 6.2.1 Transition Metals
                                                                                                                                                                                                                                                                                • 6.2.2 Transition Metal Complexes
                                                                                                                                                                                                                                                                                  • 6.2.3 Coloured Ions
                                                                                                                                                                                                                                                                                    • 6.2.4 Ligands
                                                                                                                                                                                                                                                                                      • 6.2.5 Octahedral Complexes
                                                                                                                                                                                                                                                                                        • 6.2.6 Tetrahedral Complexes
                                                                                                                                                                                                                                                                                          • 6.2.7 Cis-platin
                                                                                                                                                                                                                                                                                            • 6.2.8 Haemoglobin
                                                                                                                                                                                                                                                                                              • 6.2.9 Catalysis
                                                                                                                                                                                                                                                                                                • 6.2.10 Heterogeneous Catalysis
                                                                                                                                                                                                                                                                                                  • 6.2.11 Homogeneous Catalysis
                                                                                                                                                                                                                                                                                                    • 6.2.12 Autocatalysis
                                                                                                                                                                                                                                                                                                    • 6.3 Reactions of Transition Metal Elements
                                                                                                                                                                                                                                                                                                      • 6.3.1 Vanadium
                                                                                                                                                                                                                                                                                                        • 6.3.2 Chromium
                                                                                                                                                                                                                                                                                                          • 6.3.3 Reactions of Ions in Aqueous Solution
                                                                                                                                                                                                                                                                                                            • 6.3.4 Ligand Exchange
                                                                                                                                                                                                                                                                                                          • 7. Advanced Organic Chemistry (A Level Only)
                                                                                                                                                                                                                                                                                                            • 7.1 Organic Chemistry II: Chirality
                                                                                                                                                                                                                                                                                                              • 7.1.1 Chirality
                                                                                                                                                                                                                                                                                                              • 7.2 Organic Chemistry II: Carbonyl Chemistry
                                                                                                                                                                                                                                                                                                                • 7.2.1 Carbonyl Compounds
                                                                                                                                                                                                                                                                                                                  • 7.2.2 Testing for Carbonyls
                                                                                                                                                                                                                                                                                                                  • 7.3 Organic Chemistry II: Carboxylic Acids
                                                                                                                                                                                                                                                                                                                    • 7.3.1 Physical Properties of Carboxylic Acids
                                                                                                                                                                                                                                                                                                                      • 7.3.2 Preparation of Carboxylic Acids
                                                                                                                                                                                                                                                                                                                        • 7.3.3 Reactions of Carboxylic Acids
                                                                                                                                                                                                                                                                                                                          • 7.3.4 Acyl Chlorides & Esters
                                                                                                                                                                                                                                                                                                                          • 7.4 Organic Chemistry III: Aromatic Chemistry
                                                                                                                                                                                                                                                                                                                            • 7.4.1 Benzene Structure
                                                                                                                                                                                                                                                                                                                              • 7.4.2 Reactions of Benzene
                                                                                                                                                                                                                                                                                                                                • 7.4.3 Electrophilic Substitution
                                                                                                                                                                                                                                                                                                                                  • 7.4.4 Phenol
                                                                                                                                                                                                                                                                                                                                  • 7.5 Organic Chemistry III: Nitrogen Chemistry
                                                                                                                                                                                                                                                                                                                                    • 7.5.1 Amines, Amides, Amino Acids & Proteins
                                                                                                                                                                                                                                                                                                                                      • 7.5.2 Primary Aliphatic Amines
                                                                                                                                                                                                                                                                                                                                        • 7.5.3 Amine Basicity
                                                                                                                                                                                                                                                                                                                                          • 7.5.4 Aromatic Amine Formation
                                                                                                                                                                                                                                                                                                                                            • 7.5.5 Amide Chemistry
                                                                                                                                                                                                                                                                                                                                              • 7.5.6 Condensation Polymerisation
                                                                                                                                                                                                                                                                                                                                                • 7.5.7 Amino Acids & Proteins
                                                                                                                                                                                                                                                                                                                                                • 7.6 Organic Chemistry III: Organic Synthesis
                                                                                                                                                                                                                                                                                                                                                  • 7.6.1 Deducing Organic Structures
                                                                                                                                                                                                                                                                                                                                                    • 7.6.2 Planning Reaction Schemes
                                                                                                                                                                                                                                                                                                                                                      • 7.6.3 Increasing Chain Length
                                                                                                                                                                                                                                                                                                                                                        • 7.6.4 Organic Techniques - Preparation
                                                                                                                                                                                                                                                                                                                                                          • 7.6.5 Organic Techniques - Purification
                                                                                                                                                                                                                                                                                                                                                            • 7.6.6 Organic Techniques - Purity
                                                                                                                                                                                                                                                                                                                                                            • 7.7 Modern Analytical Techniques II
                                                                                                                                                                                                                                                                                                                                                              • 7.7.1 Mass Spectrometry
                                                                                                                                                                                                                                                                                                                                                                • 7.7.2 Carbon-13 NMR
                                                                                                                                                                                                                                                                                                                                                                  • 7.7.3 Proton NMR
                                                                                                                                                                                                                                                                                                                                                                    • 7.7.4 Thin-Layer Chromatography
                                                                                                                                                                                                                                                                                                                                                                      • 7.7.5 Other Chromatography
                                                                                                                                                                                                                                                                                                                                                                    • 8. Advanced Core Practicals (A Level Only)
                                                                                                                                                                                                                                                                                                                                                                      • 8.1 Advanced Physical Chemistry Core Practicals
                                                                                                                                                                                                                                                                                                                                                                        • 8.1.1 Finding Ka Values
                                                                                                                                                                                                                                                                                                                                                                          • 8.1.2 Electrochemical Cells
                                                                                                                                                                                                                                                                                                                                                                            • 8.1.3 Rates of Reaction
                                                                                                                                                                                                                                                                                                                                                                              • 8.1.4 Activation Energy
                                                                                                                                                                                                                                                                                                                                                                              • 8.2 Advanced Inorganic & Organic Chemistry Core Practicals
                                                                                                                                                                                                                                                                                                                                                                                • 8.2.1 Redox Titration
                                                                                                                                                                                                                                                                                                                                                                                  • 8.2.2 Transition Metal Complexes
                                                                                                                                                                                                                                                                                                                                                                                    • 8.2.3 A-Level Qualitative Analysis
                                                                                                                                                                                                                                                                                                                                                                                      • 8.2.4 Aspirin Preparation


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                                                                                                                                                                                                                                                                                                                                                                                    Author: Richard

                                                                                                                                                                                                                                                                                                                                                                                    Richard has taught Chemistry for over 15 years as well as working as a science tutor, examiner, content creator and author. He wasn’t the greatest at exams and only discovered how to revise in his final year at university. That knowledge made him want to help students learn how to revise, challenge them to think about what they actually know and hopefully succeed; so here he is, happily, at SME.


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