AQA A Level Chemistry

Topic Questions

8.2 Inorganic Chemistry Practicals (A Level only)

1a2 marks

Potassium manganate(VII), KMnO4 (aq), will oxidise ethanedioic acid, to carbon dioxide and water, in the presence of an excess of acid as shown in the equation 

2MnO4- (aq) + 5C2O42- (aq) + 16H+ (aq) → 2Mn2+ (aq)  + 10CO2 (g) + 8H2O (I)

This reaction is initially slow and then the rate of reaction increases once manganese(II),  Mn2+, ions are produced.

Explain why the initial rate of reaction is slow.

1b1 mark

The rate of reaction can be represented by the graph shown in Figure 1.

Figure 1

8-2-aqa-a-level-chemistry-sq-q1b-easy

Identify the curve on the graph in Figure 1 which shows the reaction that occurs in part (a).

1c1 mark

One method of measuring the rate of the reaction outlined in part (a) is to remove samples at different times and carry out a titration using sodium thiosulphate.

State an alternative method that can be used to monitor the course of the reaction.

1d5 marks

Draw a labelled diagram to show the set up of your method named in part (c)

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2a3 marks

Table 1 shows the reactions and typical pH values for magnesium, aluminium and silicon. Complete Table 1.

Table 1

Element

Mg

Al

Si

Observation for reaction with oxygen

 

 

White powder produced

pH of aqueous solution of oxide

8

7

 

 

2b1 mark

Explain why the pH of aluminium oxide is 7 when added to water.

2c4 marks

Describe how a student could carry out the reaction of sulfur with oxygen.

2d1 mark

A solution containing sulfur dioxide, SO2 (aq), reacts with sodium hydroxide, NaOH (aq) as follows

SO2 (aq) + NaOH (aq) → NaHSO3 (aq)

Write an equation to show the further reaction of sodium hydrogensulfate(IV), NaHSO3 (aq), to produce sodium sulfate(IV), Na2SO3 (aq). 

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3a2 marks

Potassium dichromate was used to titrate a sample containing an unknown percentage of iron.

The sample is dissolved in sulfuric acid to oxidise all of the iron to Fe2+ ions. The solution is then titrated with 0.02 mol dm-3 K2Cr2O7, producing Fe3+ and Cr3+ ions in acidic solution.

The titration requires 31.00 cm3 of K2Cr2O7 for 1.35 g of the sample.

Write half equations for the oxidation of Fe2+ ions to Fe3+ and the reduction of Cr2O72- ions to Cr3+.

3b1 mark

Using your answer to part (a) write the full equation for the reaction between Fe2+ ions and Cr2O72- ions. 

3c2 marks

Using the information in part (a), calculate the number of moles of potassium dichromate, K2Cr2O7 used and hence the number of moles of Fe2+ in the sample.

3d3 marks

Using the information in part (a) calculate the percentage of iron in the original sample.
Give your answer to 3 significant figures. 

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4a3 marks

A student carried out the following experiment to identify separate samples of iron(III) nitrate, Fe(NO3)3 (aq), and ammonium iron(II) sulfate, (NH4)2Fe(SO4)2(H2O)6 (aq).

Ten drops of sodium carbonate solution, Na2CO3 (aq), were added to to each solution separately.

State the observations the student made.

4b2 marks

The student then added sodium hydroxide, in excess, to a new sample of each solution in clean test tubes. 

State the observations for each of the solutions given in part (a).

4c2 marks

The test tubes containing the solutions in part (b) were then left to stand in beakers of hot water. Which solution will show a change and state the observation for this solution.

4d1 mark

A solution containing an unknown compound was placed into two clean test tubes. Ten drops of silver nitrate were added to one test tube and a white precipitate was observed.
Dilute ammonia was added and the white precipitate dissolved.

Ten drops of sodium carbonate solution was added to the other test tube and a blue-green precipitate was seen.

State the formula of the unknown compound.

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5a2 marks

A student performed a series of ligand substitution reactions, as described below.

  • The student placed 2.0 cm3 of 1.0 mol dm-3 aqueous copper(II) complex, [Cu(H2O)6]2+, into a clean test tube
  • They added 1.0 mol dm-3 ammonia solution drop wise
  • They recorded any observations.
  • They then continued adding the 1.0 mol dm-3 ammonia solution until it was in excess
  • They, again, recorded any observations.

State the observations that the student made, when ammonia solution was added dropwise and then to excess.

5b2 marks

Write an equation for the reaction of excess ammonia with [Cu(H2O)6]2+ and state the shape of the product.

5c2 marks

The student then measured 2.0 cm3 of 1.0 mol dm-3 of the same aqueous copper complex, [Cu(H2O)6]2+, to a clean test tube and added concentration hydrochloric acid drop wise.

State the observations the student made and give the formula of the resulting aqueous copper complex.

5d3 marks

Name the three factors that affect the colour formed for different transition metal ion solutions.

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1a2 marks

Write two equations to demonstrate the amphoteric nature of aluminium oxide.

1b4 marks

Outline the mechanism to show how an aqueous Al3+ ion can act as a Brønsted-Lowry acid.

1c6 marks

Outline an experiment to determine the pH of the period three oxides. Include expected results and equations in your answer.

1d4 marks

Explain how it is possible to establish the purity of a sample of P4O10.

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2a1 mark

Write an equation for the reaction between ethanedioic acid, H2C2O4, and sodium hydroxide, NaOH.

2b3 marks

15.00 cm3 of a H2C2O4 requires 10.30 cm3 of a 0.25 mol dm-3 solution of NaOH for complete neutralisation using a phenolphthalein indicator for the first permanent colour change.

15.00 cm3 of the same H2C2O4 solution required 12.35 cm3 of potassium permanganate, KMnO4, solution for complete oxidation to carbon dioxide and water in the presence of dilute sulfuric acid to further acidify the H2C2O4 solution for the first permanent colour change.

Calculate the moles of H2C2O4 in the solution and therefore the concentration of the solution. 

2c3 marks

Write the full redox equation, including state symbols, for this redox titration.

2d2 marks

Calculate the concentration of the potassium permanganate, KMnO4, solution. 

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3a1 mark

Vanadium is a transition metal with oxidation states ranging from +5 to +2, which can each be identified by the colour of the solution that they form.

State the formula of ammonium vanadate(V).

3b3 marks

A demonstration of the oxidation states of vanadium was carried out in a fume hood against a white background to help observe the colour changes.

Ammonium vanadate(V) is not very soluble in water. A quarter spatula of ammonium vanadate was mixed with 1.0 mol dm-3 hydrochloric acid forming a yellow solution containing the dioxovanadium(V) ion, VO2+.

An excess of zinc powder was added and the test tube was again shaken. Over a period of fifteen minutes the colours changed from yellow to green to blue to green and finally violet.

Using the data in Table 1, explain the first reaction that takes place after the addition of the excess zinc powder.

Your answer should include oxidation states and relevant equations.

Table 1

Zn2+ (aq) + 2e- ⇌ Zn (s)

EӨ = -0.76 V

V3+ (aq) + e- ⇌ V2+ (aq)

EӨ = -0.26 V

Sn2+ (aq) + 2e- ⇌ Sn (s)

EӨ = -0.14 V

VO2+ (aq) + 2H+ (aq) + e- ⇌ H2O (l) + V3+ (aq)

EӨ = +0.34 V

VO2+ (aq) + 2H+ (aq) + e- ⇌ H2O (l) + VO2+ (aq)

EӨ = +1.00 V



3c1 mark

During the demonstration described in part (b), a colour change from yellow to green is observed. Explain this colour change. 

3d3 marks

The experiment outlined in part (b) was repeated and zinc was replaced with tin.

Use the redox potentials in Table 1, part (b), to explain the extent to which tin can reduce the dioxovanadium(V) ion, VO2+.

Your answer should include any expected colour changes.

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4a8 marks

A student carried out a series of experiments to identify four different transition metal compounds. Table 1 shows the student’s results which include incorrect and incomplete observations.

Identify the transition metal ions in each compound and correct the student’s observations.

Table 1

Compound

Action of NaOH

Action of excess NH3 (aq)

Action of Na2CO3 (aq)

A

Brown ppt

Brown ppt

Gas evolved

B

White ppt

White ppt

Gas evolved

C

Blue ppt

Dark blue ppt

Blue green ppt and gas evolved

D

Green ppt

Green ppt

Green ppt

 

4b3 marks

Write an equation, including state symbols, for the separate reactions between the aqueous transition metal complex of Compound C with the following reagents:

i)
Ammonia

ii)
Excess ammonia 

iii)
Sodium carbonate solution  
4c2 marks

Write an equation for the reaction between the aqueous transition metal complex of Compound B with sodium carbonate solution to produce the white precipitate observed.

4d3 marks

Explain why compound A releases a gas when reacted with sodium carbonate solution. 

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5a4 marks

A sample of rusted iron was analysed to determine the percentage of iron that had been oxidised to hydrated iron(III) oxide. A small amount of this sample was dissolved in excess sulfuric acid to give 500 cm3 of solution. This solution contains both Fe2+ and Fe3+ ions.

20.00 cm3 of this solution required 18.05 cm3 of 0.05 mol dm-3 potassium permanganate for complete oxidation.

An oxidising agent was also added to a second 20.00 cm3 of the rust solution to convert
all of the Fe2+ ions to Fe3+ ions. The Fe3+ ions reacted with 18.40 cm3 of 0.05 mol dm-3 of EDTA4- ions.

Write the full equation for the reaction between iron(II) ions and manganate(VII) ions

Calculate the number of moles of Fe2+ ions present in the sample titrated against potassium permanganate.

5b1 mark

Assuming 1 mole of EDTA reacts with 1 mole of Fe3+ ions, calculate the moles of Fe3+ ions present in the second solution. 

5c2 marks

Using your answers to part (a) and part (b) calculate the percentage of rust in the original sample of rusted iron. 

5d3 marks

Using the redox potentials given in Table 1, explain why hydrochloric acid is not a suitable choice for this titration. Your answer should include relevant equations.

Table 1

Fe3+ (aq) + e- ⇌ Fe2+ (aq)

EӨ = +0.77 V

½ Cl2 (aq) + e- ⇌ Cl - (aq)

EӨ = +1.36 V

MnO4- + 8H+ + 5e- ⇌ Mn2+ + 4H2O

EӨ = +1.54 V

 

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1a2 marks

The most common oxidation states of iron in iron compounds are +2 and +3. Iron(II)ions are readily oxidised to iron(III). 

Write full electronic configurations for Fe2+ and Fe3+ ions and explain their relative stabilities.

1b2 marks

Iron(II) ions may be oxidised by bubbling chlorine gas through an aqueous solution of the ions.

Write an ionic equation to represent the reaction and state the colour change which would occur.

1c4 marks

Describe, including equations, how it is possible to distinguish between Fe2+ and Fe3+ ions using aqueous sodium hydroxide solution.

1d6 marks

The concentration of iron in iron supplement tablets can be determined using colorimetry of a complex of iron with thiocyanate ions;

Fe3+ + SCN- → [FeSCN]2+

Outline a method which could be used.

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2a3 marks

Water pipes can release lead, copper and zinc ions as a result of containing acidic drinking water.  Describe how you could detect aqueous copper(II) ions in a solution using aqueous sodium hydroxide solution, including an equation in your answer.

2b4 marks

The concentration of copper(II) ions in solution can be determined by titration with a standard solution of EDTA.

The equipment used for this experiment is shown in Figure 1 below.

Figure 1

8-2-aqa-a-level-chemistry-sq-q2b-medium

i)
Write an equation for the reaction of aqueous Cu2+ ions with EDTA solution. 

ii)
The concentration of Cu2+ ions in a sample of water was 21 mg dm-3.  Calculate the volume of 0.001 mol dm-3 EDTA solution required to completely react with a 100 cm3 sample of water. 
2c2 marks

Explain why the complex formed between copper(II) ions and EDTA is more stable than the complex in the aqueous solution.

2d2 marks

Aqueous copper(II) ions will react with aqueous sodium carbonate to form a precipitate. 
Give one observation associated with this reaction and write a balanced symbol equation to represent the reaction.

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3a3 marks

The percentage of iron in a steel wire can be determined from a redox titration using acidified potassium manganate(VII) solution. 

i)
Write an ionic equation to represent the reaction. 

ii)
State and explain the colour change that occurs at the end point of this titration. 
3b2 marks

Explain why the iron wire is dissolved in an excess of sulfuric acid and not ethanoic acid.

3c5 marks

1.60 g of iron wire was dissolved in an excess of dilute sulfuric acid and the solution made up to 250 cm3. A 25.0 cm3 portion of this solution required 26.0 cm3 of 0.02 mol dm–3 potassium manganate(VII) solution for complete reaction.

Calculate the percentage of iron in the steel wire.

3d2 marks

If an excess of sodium hydroxide is added to the flask after the titration is completed it will react with both manganese(II) and iron(III) ions.   Deduce what would be observed and write an equation, including state symbols for the reaction which would be taking place when the sodium hydroxide reacts with the iron(III) ions.

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4a4 marks

Malachite has the formula CuCO3.Cu(OH)2 and is readily converted to copper (II) oxide by heating.  The oxide can be reduced to copper by heating strongly with carbon.

i)
Calculate the percentage of copper in malachite. 

ii)
Write an equation for the action of heat on malachite. 

iii)
Write an equation for the reduction of copper(II) oxide by carbon. 
4b4 marks

Malachite dissolves in nitric acid to form a solution of copper(II) nitrate.  When excess aqueous ammonia is added dropwise to the solution colour changes occur.

State and explain the observations of adding the ammonia solution until in excess and write equations for the reactions that occur.

4c2 marks

Redox potentials are used to predict chemical reactions.  Use the standard electrode potentials below to write an equation for the reaction which occurs when bromine is added to aqueous iron(II) ions and deduce the EMF.

Fe2+(aq) + 2e- ⇌Fe(s)             Eϴ = -0.44 V

Fe3+(aq) + e- ⇌ Fe2+(aq)         Eϴ = +0.77 V

Br2(aq) + 2e- ⇌ 2Br-(aq)          Eϴ = +1.09 V

4d3 marks

Ethanedioic acid,H2C2O4, is used commercially as a laundry rinse, wood-bleaching agent and limescale remover.  The ethanedioate ion, C2O42-, is a bidentate ligand and can participate in ligand substitution reactions.

Fe3+(aq) + e- ⇌ Fe2+(aq)         Eϴ = +0.77 V

2CO2(g) + 2e- ⇌  C2O42-(aq)   Eϴ = -0.49 V

i)
Write an equation for the ligand substitution reaction that would take place for the reaction of aqueous iron(II) ions and ethanedioate ions. 

ii)
Aqueous iron(III) ions will not form a complex when mixed with ethanedioate ions.  Use the standard electrode potentials to explain why. 

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5a1 mark

A sample of phosphorus(V) oxide was prepared in the laboratory using white phosphorus (P4) which is a hazardous form of the element.

Give one reason why white phosphorus is stored under water.

5b2 marks

Give an equation and state one observation for the complete reaction of phosphorus with air.

5c3 marks

Phosphorus(V) oxide has a melting point of 300 oC.  Outline a suitable method to determine the melting point of the sample produced and its link to the purity of the sample.

5d4 marks

Phosphorus(V) oxide is an acidic oxide. 

i)

Describe briefly an experiment that can be carried out in the laboratory to confirm the acidity.

ii)
Write an equation for the reaction of phosphorus(V) oxide with the base sodium oxide. 

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